产品名称
三正丁基氢化锗, 99%
InChI
1S/C12H28Ge/c1-4-7-10-13(11-8-5-2)12-9-6-3/h13H,4-12H2,1-3H3
SMILES string
CCCC[GeH](CCCC)CCCC
InChI key
KTSWILXIWHVQLR-UHFFFAOYSA-N
assay
99%
form
liquid
reaction suitability
core: germanium
reagent type: reductant
refractive index
n20/D 1.45 (lit.)
bp
123 °C/20 mmHg (lit.)
density
0.949 g/mL at 25 °C (lit.)
Quality Level
Application
苄基氯化物的有效还原剂。
General description
Tributylgermanium hydride is a radical generating reagent. Reductive alkylation of active olefins with alkyl halides with tributylgermanium hydride was investigated in detail.
Packaging
Packaged in glass bottles
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Angewandte Chemie (International Edition in English), 31, 1046-1046 (1992)
Evaluation of tributylgermanium hydride as a reagent for the reductive alkylation of active olefins with alkyl halides
Pike P, et al.
Tetrahedron, 44(20), 6295-6304 (1988)
Tributylgermanium hydride as a replacement for tributyltin hydride in radical reactions.
Bowman WR, et al.
Organic & Biomolecular Chemistry, 2(4), 585-592 (2004)
Theresia Ahrens et al.
Dalton transactions (Cambridge, England : 2003), 45(43), 17495-17507 (2016-11-02)
The reaction of the silyl complex [Rh{Si(OEt)
商品
High Purity Metalorganic Precursors for CPV Device Fabrication
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