所有图片(2)
About This Item
线性分子式:
[CH3(CH2)3]3GeH
CAS号:
分子量:
244.99
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
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方案
99%
表单
liquid
反应适用性
core: germanium
reagent type: reductant
折射率
n20/D 1.45 (lit.)
沸点
123 °C/20 mmHg (lit.)
密度
0.949 g/mL at 25 °C (lit.)
SMILES字符串
CCCC[GeH](CCCC)CCCC
InChI
1S/C12H28Ge/c1-4-7-10-13(11-8-5-2)12-9-6-3/h13H,4-12H2,1-3H3
InChI key
KTSWILXIWHVQLR-UHFFFAOYSA-N
一般描述
Tributylgermanium hydride is a radical generating reagent. Reductive alkylation of active olefins with alkyl halides with tributylgermanium hydride was investigated in detail.
应用
苄基氯化物的有效还原剂。
包装
Packaged in glass bottles
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Angewandte Chemie (International Edition in English), 31, 1046-1046 (1992)
Tributylgermanium hydride as a replacement for tributyltin hydride in radical reactions.
Bowman WR, et al.
Organic & Biomolecular Chemistry, 2(4), 585-592 (2004)
Evaluation of tributylgermanium hydride as a reagent for the reductive alkylation of active olefins with alkyl halides
Pike P, et al.
Tetrahedron, 44(20), 6295-6304 (1988)
Theresia Ahrens et al.
Dalton transactions (Cambridge, England : 2003), 45(43), 17495-17507 (2016-11-02)
The reaction of the silyl complex [Rh{Si(OEt)
商品
High Purity Metalorganic Precursors for CPV Device Fabrication
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