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401781

双（五甲基环戊二烯基）钴 (II)

Name: 双（五甲基环戊二烯基）钴 (II)
Brand: ALDRICH

别名:

CoCp*₂, 双(五甲基环戊烯)钴

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About This Item

经验公式（希尔记法）:

C₂₀H₃₀Co

CAS号:

74507-62-3

分子量:

329.39

MDL编号:

MFCD02093610

UNSPSC代码:

12352103

PubChem化学物质编号:

24864881

NACRES:

NA.23

形式

solid

质量水平

200

反应适用性

core: cobalt

mp

>210 °C (lit.)

储存温度

2-8°C

SMILES字符串

[Co].C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C

InChI

1S/2C10H15.Co/c2*1-6-7(2)9(4)10(5)8(6)3;/h2*1-5H3;

InChI key

XDHJNPINFJSJJB-UHFFFAOYSA-N

一般描述

双（五甲基环戊二烯）钴（II）是一种功能强大的电子供体，由于其低固态电离能（3.3 eV）被广泛用作制备分子半导体的掺杂剂。该掺杂剂改善电子设备中电荷的注入和迁移。

应用

双（五甲基环戊二烯）钴（II）可用作：

作为n型掺杂剂用于制造有机电子材料，如酞菁铜薄膜。
作为还原剂用于在室温下合成优质的还原氧化石墨烯。
用于钴的等离子体增强原子层沉积的金属有机物前体。

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

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Plasma-enhanced atomic layer deposition of Co using Co(MeCp)2 precursor

Jusang Park, et al.

Journal of Energy Chemistry, 22, 403-407 (2013)

Decamethylcobaltocene as an efficient n-dopant in organic electronic materials and devices

Calvin K. Chan, et al.

Organic Electronics, 9, 575-581 (2008)

Reduction of Graphene Oxide Thin Films by Cobaltocene and Decamethylcobaltocene

Molly M. MacInnes, et al.

ACS Applied Materials & Interfaces, 10, 2004-2015 (2018)

Cation Effects on the Reduction of Colloidal ZnO Nanocrystals.

Carolyn N Valdez et al.

Journal of the American Chemical Society, 140(28), 8924-8933 (2018-06-20)

The effects of a variety of monatomic cations (H+, Li+, Na+, K+, Mg2+, and Ca2+) and larger cations (decamethylcobaltocenium and tetrabutylammonium) on the reduction of colloidal ZnO nanocrystals (NCs) are described. Suspensions of "TOPO"-capped ZnO NCs in toluene/THF were treated

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