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Merck
CN
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文件

399191

Sigma-Aldrich

三氟乙酸铑(II)二聚体

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别名:
三氟乙酸铑(II)盐二聚体
线性分子式:
[(CF3COO)2Rh]2
CAS号:
31126-95-1
分子量:
657.87
MDL编号:
MFCD00209611
UNSPSC代码:
12352300
PubChem化学物质编号:
24864793
NACRES:
NA.23

质量水平

100

形式

powder

反应适用性

reagent type: catalyst

SMILES字符串

FC(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)F.FC(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)F

InChI

1S/4C2HF3O2.2Rh/c4*3-2(4,5)1(6)7;;/h4*(H,6,7);;/q;;;;2*+2/p-4

InChI key

PQEXTYUESSEHKW-UHFFFAOYSA-J

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相关类别

应用

用于制备异构体纯的 α,β-不饱和羰基化合物以及一、二、三维分子固体的结构单元。

其他说明

含有痕量乙酸铑

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Li-Feng Mao et al.
Inorganic chemistry, 35(11), 3183-3187 (1996-05-22)
The complexes trans-[MI(2)(CNC(6)H(4)-CN-4)(2)], (M = Pd and Pt), trans-[FeI(2)L(4)] (L = CNC(6)H(4)-CN-4 and CNC(6)H(2)-Me(2)-2,6-CN-4), and [Mn(CNC(6)H(4)-CN-4)(6)][SO(3)CF(3)] were prepared. The compounds are thermally stable up to 230 degrees C or higher. The molecular structure of trans-[FeI(2)(CNC(6)H(4)-CN-4)(4)] was determined by X-ray crystallography:
A Convenient Method for the Preparation of (Z)-alpha,beta-Unsaturated Carbonyl Compounds.
Douglass F. Taber et al.
The Journal of organic chemistry, 61(8), 2908-2910 (1996-04-19)
Adam J Biacchi et al.
ACS nano, 9(2), 1707-1720 (2015-01-30)
The shapes of noble metal nanoparticles directly impact their properties and applications, including in catalysis and plasmonics, and it is therefore important to understand how multiple distinct morphologies can be controllably synthesized. Solution routes offer powerful capabilities for shape-controlled nanoparticle

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