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395021

Sigma-Aldrich

4-(二甲氨基)三苯基膦

95%

别名:

4-(Dimethylamino)triphenylphosphine

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About This Item

线性分子式:
(CH3)2NC6H4P(C6H5)2
CAS号:
739-58-2
分子量:
305.35
Beilstein:
916331
MDL编号:
MFCD00192068
UNSPSC代码:
12352116
PubChem化学物质编号:
24864636
NACRES:
NA.22

质量水平

100

方案

95%

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

151-154 °C (lit.)

官能团

phosphine

SMILES字符串

CN(C)c1ccc(cc1)P(c2ccccc2)c3ccccc3

InChI

1S/C20H20NP/c1-21(2)17-13-15-20(16-14-17)22(18-9-5-3-6-10-18)19-11-7-4-8-12-19/h3-16H,1-2H3

InChI key

GOEGBJDTWXTPHP-UHFFFAOYSA-N

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相关类别

应用

Catalyst for:
  • Preparation of dicyano(aryl)cyclohexenecarboxylic acid esters via regioselective annulation
  • Diastereoselective cycloaddition of styrenyl allenoates
  • Interfacial carbonylation of methylbenzyl bromide
  • Hydroformylation of octene

Reducing agent for selectivity of disulfide-internally linked peptide-nucleic acid cleavage

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCM2878
BCCH5931
BCCH7525
BCCF5366
BCCC4073

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Dianne Pham et al.
ACS central science, 6(10), 1772-1788 (2020-11-05)
The development of a fluorescent probe for a specific metal has required exquisite design, synthesis, and optimization of fluorogenic molecules endowed with chelating moieties with heteroatoms. These probes are generally chelation- or reactivity-based. Catalysis-based fluorescent probes have the potential to
Iris Boll et al.
Bioorganic & medicinal chemistry letters, 15(3), 505-509 (2005-01-25)
Selectivity of the cleavage of single stranded over hybridized forms of internally modified disulfide-peptide nucleic acids (PNA) has been optimized using a series of phosphines and thiols, which have different sizes and charges. For the most selective cleaver found (tris-(carboxyethyl)-phosphine)

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