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About This Item
线性分子式:
CF3CON(CH3)Si(CH3)3
CAS号:
分子量:
199.25
Beilstein:
1941550
EC 号:
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NA.22
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等级
for GC derivatization
synthesis grade
质量水平
蒸汽密度
>1 (vs air)
蒸汽压
8.8 mmHg ( 27 °C)
方案
≥98%
表单
liquid
反应适用性
reagent type: derivatization reagent
reaction type: Silylations
折射率
n20/D 1.38 (lit.)
沸点
130-132 °C (lit.)
密度
1.075 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CN(C(=O)C(F)(F)F)[Si](C)(C)C
InChI
1S/C6H12F3NOSi/c1-10(12(2,3)4)5(11)6(7,8)9/h1-4H3
InChI key
MSPCIZMDDUQPGJ-UHFFFAOYSA-N
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一般描述
N-甲基-N-(三甲基硅烷基)三氟乙酰胺(MSTFA)是一种衍生化试剂。它可以用作重氮甲烷的替代品。
应用
甲硅烷基化试剂可用于生成GC-MS分析用挥发性衍生物。
用于同时检测类固醇激素17-α-乙炔雌二醇和雌酮的改良型甲硅烷基化程序。
用于同时检测类固醇激素17-α-乙炔雌二醇和雌酮的改良型甲硅烷基化程序。
其他说明
三甲基甲硅烷基化试剂。
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
77.0 °F - closed cup
闪点(°C)
25 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Tina Kosjek et al.
Environment international, 31(5), 679-685 (2005-05-25)
Pharmacologically active substances used to treat human and animal illnesses can enter the aquatic environment via effluents from wastewater treatment plants or in the case of veterinary drugs directly through liquid manure discharge. Some of these substances enter the environment
Hee-Kyung Jeon et al.
Journal of chromatography. A, 1131(1-2), 192-202 (2006-08-08)
A novel method has been developed to simultaneously determine and quantify seven organic UV filters employing liquid (solid)-liquid extraction, derivatization with N-methyl-N-(trimethylsilyl) trifluoroacetamide (MSTFA) and gas chromatography with mass spectrometric detection in various environmental matrices. The UV filters determined were:
Iria González-Mariño et al.
Journal of chromatography. A, 1217(11), 1748-1760 (2010-02-13)
An alternative method for the sensitive determination of several drugs of abuse and some of their metabolites in surface and sewage water samples is proposed. Analytes are concentrated using a solid-phase extraction (SPE) sorbent, converted into the corresponding trimethylsilyl derivatives
Stina K Lien et al.
Journal of chromatography. A, 1247, 118-124 (2012-06-15)
GC-MS analysis of silylated metabolites is a sensitive method that covers important metabolite groups such as sugars, amino acids and non-amino organic acids, and it has become one of the most important analytical methods for exploring the metabolome. Absolute quantitative
L Damasceno et al.
Journal of mass spectrometry : JMS, 35(11), 1285-1294 (2000-12-13)
An evaluation of derivatization procedures for the detection of beta(2)-agonists is presented. The study was performed with the beta(2)-agonists bambuterol, clenbuterol, fenoterol, formoterol, salbutamol, salmeterol and terbutaline. Different derivatizating agents were employed, aiming to obtain derivatives with high selectivity to
实验方案
Alkylphenols are used in various industries like paper manufacturing and pesticide formulations.
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