393606
邻甲基苯硼酸
≥95.0%
别名:
2-甲基苯硼酸
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关于此项目
线性分子式:
CH3C6H4B(OH)2
化学文摘社编号:
分子量:
135.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
邻甲基苯硼酸, ≥95.0%
InChI
1S/C7H9BO2/c1-6-4-2-3-5-7(6)8(9)10/h2-5,9-10H,1H3
SMILES string
Cc1ccccc1B(O)O
InChI key
NSJVYHOPHZMZPN-UHFFFAOYSA-N
assay
≥95.0%
form
solid
mp
162-164 °C (lit.)
Quality Level
Application
作为试剂用于以下反应
试剂用于制备
- 钯催化的吡唑与苯硼酸的直接芳基化反应
- 水中 Suzuki-Miyaura 交叉偶联的钯催化芳基化
- 钌催化的直接芳基化反应
- 无配体铜催化的偶联反应
- 铜催化的二芳基二硒醚交叉偶联反应
- 不含磷的Suzuki-Miyaura交叉偶联反应
- 铑催化的不对称 1,4-加成反应
试剂用于制备
- 不对称 Suzuki-Miyaura 偶联反应中的手性单磷配体
- 通过点击离子共聚物固定的钯纳米颗粒，用于在水中进行 Suzuki-Miyaura 交叉偶联反应的循环催化剂
- 人法呢基焦磷酸合酶抑制剂，作为多发性骨髓瘤细胞的抗肿瘤药
Other Notes
含有不定量的酸酐。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Yih-Shyan Lin et al.
Journal of medicinal chemistry, 55(7), 3201-3215 (2012-03-07)
Human farnesyl pyrophosphate synthase (hFPPS) controls intracellular levels of FPP and post-translational prenylation of small GTPase proteins, which are essential for cell signaling and cell proliferation. Clinical investigations provide evidence that N-BP inhibitors of hFPPS are disease modifying agents that
Xinwei Tian et al.
Journal of agricultural and food chemistry, 65(43), 9553-9558 (2017-10-11)
A novel near-infrared fluorescence off-on probe, (E)-3,3-dimethyl-1-propyl-2-(2-(6-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzyloxy)-2,3-dihydro-1H-xanthen-4-yl)vinyl)-3H-indolium (1), is developed and applied to benzoyl peroxide (BPO) detection in real samples and fluorescence imaging in living cells and zebrafish. When arylboronate as the recognition unit is connected to a stable hemicyanine
Tetrahedron, 63, 6996-6996 (2007)
Wenjun Tang et al.
Organic letters, 14(9), 2258-2261 (2012-04-14)
A series of novel P-chiral monophosphorus ligands exhibit efficiency in asymmetric Suzuki-Miyaura coupling reactions, enabling the construction of an array of chiral biaryl products in high yields and excellent enantioselectivities (up to 96% ee) under mild conditions. The carbonyl-benzooxazolidinone moiety
Glycerol as a recyclable solvent for copper-catalyzed cross-coupling reactions of diaryl diselenides with aryl boronic acids
Ricordi, V. G.; et al.
Green Chemistry, 14, 1030-1034 (2012)
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