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质量水平
检测方案
97%
形式
liquid
反应适用性
reagent type: ligand
reaction type: Reductions
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Wittig Reaction
折射率
n20/D 1.463 (lit.)
bp
48-50 °C/12 mmHg (lit.)
密度
0.898 g/mL at 25 °C (lit.)
官能团
phosphine
SMILES字符串
CN(C)P(N(C)C)N(C)C
InChI
1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
InChI key
XVDBWWRIXBMVJV-UHFFFAOYSA-N
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应用
三(二甲胺基)膦可与CCl4结合使用,作为试剂,将羟基转化为相应氯化物;用于羟基活化;脱水。
三(二甲胺基)膦可用作:
- 制备芳烃-钌(II)配合物的配体,这一配合物作为催化剂用于腈水合成酰胺。
- 作为磷来源,与InCl3 一起合成InP胶体量子点(QDs)。
- 作为脱氧剂,在富勒烯C60存在的条件,用于某些 α-二羰基化合物。
警示用语:
Danger
危险分类
Carc. 1B - Eye Irrit. 2 - Flam. Liq. 3 - Muta. 1B - Skin Irrit. 2
WGK
WGK 3
闪点(°F)
80.6 °F
闪点(°C)
27 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Organometallic synthesis of InP quantum dots using tris (dimethylamino) phosphine as a phosphorus source.
Chemistry Letters (Jpn), 33(11), 1492-1493 (2004)
Arene-ruthenium (ii) complexes containing inexpensive tris (dimethylamino) phosphine: highly efficient catalysts for the selective hydration of nitriles into amides.
Organometallics, 30(20), 5442-5451 (2011)
The Journal of organic chemistry, 76(8), 2548-2557 (2011-03-12)
The reactions of such cyclic α-diketones as acenaphthenequinone, aceanthrenequinone, and N-alkylisatins, with hexaethyltriaminophosphine in the presence of the fullerene C(60), lead to the formation of methanofullerene derivatives under mild conditions. This process proceeds via deoxygenation of the dicarbonyl compound by
相关内容
The Catalexis platform enhances catalysis by digitally optimizing catalyst selection to identify the most effective phosphine ligands for cross-coupling reactions.
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