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Merck
CN
所有图片(2)

文件

392960

Sigma-Aldrich

二苯基-2-吡啶膦

97%

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别名:
2-(Diphenylphosphino)pyridine, 2-Pyridyldiphenylphosphine, Diphenyl(2-pyridinyl)phosphine
经验公式（希尔记法）:
C17H14NP
CAS号:
37943-90-1
分子量:
263.27
MDL编号:
MFCD00192108
UNSPSC代码:
12352005
PubChem化学物质编号:
24864153
NACRES:
NA.22

质量水平

100

检测方案

97%

形式

solid

反应适用性

reagent type: ligand
reaction type: Carbonatations
reagent type: ligand
reaction type: Dehydrogenation
reagent type: ligand
reaction type: Hydration Reaction
reagent type: ligand
reaction type: Mitsunobu Reaction
reagent type: ligand
reaction type: Stannylation

杂质

1-3% 2-bromopyridine

mp

82-84 °C (dec.) (lit.)

官能团

phosphine

SMILES字符串

c1ccc(cc1)P(c2ccccc2)c3ccccn3

InChI

1S/C17H14NP/c1-3-9-15(10-4-1)19(16-11-5-2-6-12-16)17-13-7-8-14-18-17/h1-14H

InChI key

SVABQOITNJTVNJ-UHFFFAOYSA-N

相关类别

应用

金属催化羰基化、水合、脱氢偶联、碳甲锡烷基化、二甲锡烷基化和甲硅烷基化的配体；Mitsunobu反应的试剂。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险分类

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Oshiki, T.; Yamashita, H. et al.
Organometallics, 24, 6287-6287 (2005)
Hiroto Yoshida et al.
Organic letters, 8(18), 4157-4159 (2006-08-25)
An exo-diene moiety of various ortho-quinodimethanes, regardless of its transient character, was inserted into a Sn-Sn sigma-bond of hexabutyldistannane in the presence of a palladium catalyst, giving alpha,alpha'-bis(tributylstannyl)-o-xylenes straightforwardly.
Nickel-catalyzed tandem carbostannylation of alkynes and 1,2-dienes with alkynylstannanes.
Eiji Shirakawa et al.
Angewandte Chemie (International ed. in English), 43(26), 3448-3451 (2004-06-29)
Consorti, C. S.; Ebeling, G.; Dupont, J.
Tetrahedron Letters, 43, 753-753 (2002)
Xianjin Lan et al.
Journal of hazardous materials, 375, 26-32 (2019-04-30)
The worldwide environmental occurrence of natural steroid estrogens has drawn increasing concerns. However, the fate of the estrogens, especially the α-isomer of estradiol, in the environmental matrices is still obscure. Using 14C-radioactively labelled forms of these estrogens can facilitate and

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Catalexis Catalyst Screening Platform

The Catalexis platform enhances catalysis by digitally optimizing catalyst selection to identify the most effective phosphine ligands for cross-coupling reactions.

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