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Merck
CN
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文件

安全信息

380768

Sigma-Aldrich

二苯基磷酸钾 溶液

0.5 M in THF

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别名:
二苯基膦钾, KPPh2, 二苯基磷 钾盐
线性分子式:
(C6H5)2PK
CAS号:
15475-27-1
分子量:
224.28
Beilstein:
4164304
MDL编号:
MFCD00134530
UNSPSC代码:
12352002
PubChem化学物质编号:
24863767
NACRES:
NA.22

形式

liquid

质量水平

100

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

浓度

0.5 M in THF

密度

0.929 g/mL at 25 °C

官能团

phosphine

SMILES字符串

[K]P(c1ccccc1)c2ccccc2

InChI

1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1

InChI key

FCLYZQXPJKJTDR-UHFFFAOYSA-N

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相关类别

应用


  • Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009).

  • Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007).

  • Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004).


警示用语：

Danger

危险分类

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

补充剂危害

EUH018,EUH019

WGK

WGK 3

闪点(°F)

-4.0 °F

闪点(°C)

-20 °C

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Synlett, 509-509 (1993)
Tetrahedron, 50, 799-799 (1994)
Organometallics, 13, 2928-2928 (1994)
The Journal of Organic Chemistry, 58, 5832-5832 (1993)

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