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Merck
CN
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文件

379670

Sigma-Aldrich

[1,1′-双(二苯基膦)二茂铁]二氯化钯(II)二氯甲烷络合物

别名:

Pd(dppf)Cl2 · CH2Cl2, Pd(dppf)Cl2 · DCM, [1,1′-二(二苯基膦基)二氯化钯（1：1）

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About This Item

经验公式（希尔记法）:
C35H30Cl4FeP2Pd
CAS号:
95464-05-4
分子量:
816.64
MDL编号:
MFCD00792899
UNSPSC代码:
12161600
PubChem化学物质编号:
24863679
NACRES:
NA.22

形式

solid

质量水平

200

反应适用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

275-280 °C

SMILES字符串

[Fe].ClCCl.Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.CH2Cl2.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h2*1-14H;1H2;2*1H;;/q;;;;;;+2/p-2

InChI key

CWHRHCATIKFSND-UHFFFAOYSA-L

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相关类别

应用

钯催化交叉偶联反应应用指南

分析说明

催化剂，用于芳基卤化物和双(频哪醇合)二硼 (473294) 的硼化反应，以及芳基硼酯衍生物和芳基卤化物偶联生成联芳基化合物的反应。也可用于 CO 插入反应合成内酰胺以及芳基卤化物和醇的分子内偶联反应合成中环芳基醚。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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