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374598

Sigma-Aldrich

十六烷基三甲基硫酸氢铵

99%

别名:

CTAHSO4, Hexadecyltrimethylammonium hydrogen sulfate

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About This Item

线性分子式:
CH3(CH2)15N(HSO4)(CH3)3
CAS号:
68214-07-3
分子量:
381.61
EC 号:
269-286-4
MDL编号:
MFCD00134393
UNSPSC代码:
12352107
PubChem化学物质编号:
24863318
NACRES:
NA.22

质量水平

200

方案

99%

mp

250-260 °C (dec.) (lit.)

SMILES字符串

OS([O-])(=O)=O.CCCCCCCCCCCCCCCC[N+](C)(C)C

InChI

1S/C19H42N.H2O4S/c1-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20(2,3)4;1-5(2,3)4/h5-19H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1

InChI key

UCRJJNVFJGKYQT-UHFFFAOYSA-M

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应用

十六烷基三甲基硫酸氢铵常作为表面活性剂用于水介质中的有机转化反应。
应用示例：
  • 铑(I)-催化的(Z)-甲基-α-乙酰氨基肉桂酸盐的不对称氢化反应。
  • 钯催化的1,3-二苯基-2-丙烯乙酸盐与二甲基丙二酸盐的不对称烷化反应。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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分析证书(COA)

Lot/Batch Number
BCBS6746V
BCBS2618V
BCBM4295V
BCBJ7033V
BCBJ0598V

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Catalytic asymmetric alkylation in water in the presence of surfactants
Sinou D, et al.
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Influence of different types of amphiphiles on the rhodium (I) complex-catalyzed asymmetric hydrogenation of (Z)-methyl-α-acetamidocinnamate in aqueous medium
Grassert I, et al.
Tetrahedron, 49(30), 6605-6612 (1993)
Micellar effects upon oxidation of organic sulfides by anionic oxidants
Bacaloglu R, et al.
Journal of Physical Organic Chemistry, 5(4), 171-178 (1992)
Tanja Mehling et al.
Journal of chromatography. A, 1273, 66-72 (2013-01-01)
Several methods for the description of the retention behavior in micellar liquid chromatography (MLC) were described previously. Thereby, the most common are the linear solvation energy relationships (LSER). However, for the evaluation of the LSER, a number of experimental data
Yoshinori Iiguni et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 29(1), 35-39 (2013-01-11)
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