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Merck
CN

372870

Sigma-Aldrich

氯化亚铁

greener alternative

98%

别名:

二氯化铁, 氯化亚铁

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About This Item

线性分子式:
FeCl2
CAS号:
分子量:
126.75
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

98%

表单

powder

反应适用性

core: iron
reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

677 °C (lit.)

密度

3.16 g/mL at 25 °C (lit.)

环保替代产品分类

SMILES字符串

Cl[Fe]Cl

InChI

1S/2ClH.Fe/h2*1H;/q;;+2/p-2

InChI key

NMCUIPGRVMDVDB-UHFFFAOYSA-L

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一般描述

我们致力于为您提供更环保的替代产品,以符合“绿色化学的 12 项原则”的一项或多项原则要求。这种铁催化剂价格便宜且对环境友好。 点击此处了解更多信息。

应用

氯化铁可用于催化:
  • 格里纳德氏化合物的制备,如1-萘基氯化镁。
  • 在丙酮肟存在下,将2,4,6-三甲基苯酚(2,4,6-TMP)选择性氧化生成3,5-二甲基-4-羟基苯甲醛(DMHB)。
  • 用FeCl2 改性的Raney型催化剂可以催化α,β-不饱和醛的增强选择性氢化反应生成不饱和醇。

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1

储存分类代码

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

闪点(°F)

does not flash

闪点(°C)

does not flash

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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2, 4, 6-Trimethylphenol oxidation with ferrous chloride catalyst: Effect of acetoxime addition.
Li K, et al.
J. Mol. Catal. A: Chem., 241(1-2), 72-78 (2005)
Liquid-phase Selective Hydrogenation of an Aliphatic ?, ?-Unsaturated Aldehyde over Raney Cobalt Catalyst Modified with Ferrous Chloride.
Hotta K, et al.
Bulletin of the Chemical Society of Japan, 42(5), 1447-1449 (1969)
Transition metal catalyzed preparation of Grignard compounds.
Bogdanovic B, et al.
Angewandte Chemie (International Edition in English), 39(24), 4610-4612 (2000)
Gustavo A Molina et al.
Polymers, 12(4) (2020-04-15)
In this study, new polyurethanes (PUs) were prepared by using inulin and polycaprolactone as polyols. Their structure and morphology were determined by Fourier transform infrared spectroscopy (FTIR), Raman dispersive spectroscopy, Nuclear magnetic resonance spectroscopy (1H NMR and 13C NMR), and
Laurean Ilies et al.
Journal of the American Chemical Society, 134(41), 16951-16954 (2012-10-05)
Diarylalkynes are chemo- and stereoselectively hydromagnesiated in high yields at room temperature with an iron species generated in situ from FeCl(2)and EtMgBr. Functional groups such as bromide, iodide, amine, phenoxide, and alkene are well tolerated. Under similar conditions, diynes are

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实验方案

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We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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