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质量水平
方案
99%
表单
liquid
折射率
n20/D 1.531 (lit.)
密度
1.829 g/mL at 25 °C (lit.)
官能团
bromo
fluoro
SMILES字符串
Oc1cc(F)c(F)cc1Br
InChI
1S/C6H3BrF2O/c7-3-1-4(8)5(9)2-6(3)10/h1-2,10H
InChI key
FCYZOOHWUOEAOX-UHFFFAOYSA-N
一般描述
2-Bromo-4,5-difluorophenol is reported to undergo palladium-catalyzed cyclotrimerization to yield hexafluoro- and trimethoxytriphenylene derivatives.
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
177.8 °F - closed cup
闪点(°C)
81 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
The Journal of organic chemistry, 74(8), 3199-3202 (2009-03-20)
Palladium-catalyzed cocyclotrimerization of allenes with arynes has been developed for selectively synthesizing phenanthrenes. In the presence of [(allyl)PdCl](2) and P(o-tol)(3), a variety of allenes, including internal and terminal allenes, underwent the cocyclotrimerization with arynes to afford the corresponding phenanthrenes in
Efficient Palladium-Catalyzed Cyclotrimeriza-tion of Arynes: Synthesis of Triphenylenes
Angewandte Chemie (International Edition in English), 37 (1998)
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