质量水平
检测方案
97%
形式
liquid
反应适用性
reagent type: reductant
折射率
n20/D 1.489 (lit.)
bp
73 °C/5 mmHg (lit.)
密度
0.806 g/mL at 25 °C (lit.)
SMILES字符串
C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3
InChI key
SQMFULTZZQBFBM-UHFFFAOYSA-N
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一般描述
三(三甲基硅基)硅烷是一种有机硅,通常作为自由基还原剂,用于黄原酸酯,有机卤化物,异氰化物,硒化物和酰基氯化物。也用于烯烃,炔烃和二烷基酮的硅氢加成。
应用
超甲硅烷基保护基团
可用于:
可用于:
- 氢化硅烷化
- 自由基反应
- 酸性氯化物的还原
- 碳-卤键的还原
- 羰基氢化反应
- 另一种常见应用涉及在与过渡金属和主族元素络合时,三(三甲基甲硅烷基)甲硅烷基(TTMSS或超甲硅烷基)基团的使用
- 最近,超甲硅烷基被用于碳-碳键形成的反应
Tris (trimethylsilyl) silane: an efficient hydrosilylating agent of alkenes and alkynes
The Journal of Organic Chemistry, 57(14), 3994-4000 (1992)
Synlett, 91-91 (1990)
Tris (trimethylsilyl) silane. A new reducing agent
The Journal of Organic Chemistry, 53(15), 3641-3642 (1988)
Science advances, 6(34), eabc0495-eabc0495 (2020-09-03)
Three types of seemingly unyielding trade-offs have continued to challenge the rational design for circular polymers with both high chemical recyclability and high-performance properties: depolymerizability/performance, crystallinity/ductility, and stereo-disorder/crystallinity. Here, we introduce a monomer design strategy based on a bridged bicyclic
Tris(trimethylsilyl)silane
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2007)
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