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Merck
CN

358665

Sigma-Aldrich

四丁基氰化铵

95%

别名:

N,N,N-tributyl-1-butanaminium cyanide

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About This Item

线性分子式:
(CH3CH2CH2CH2)4N(CN)
CAS号:
分子量:
268.48
Beilstein:
3598808
EC 号:
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

95%

mp

89-92 °C (lit.)

SMILES字符串

[C-]#N.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.CN/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-2/h5-16H2,1-4H3;/q+1;-1

InChI key

KRRBFUJMQBDDPR-UHFFFAOYSA-N

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应用

氰化四丁基铵(TBACN)可用作比色研究中的氰离子源
也可作为反应物,制备下列物质:
  • 四丁基氟化铵(TBAF),可用于去除甲硅烷基醚保护基团
  • 基于铼的单链磁体(DMF)4MReCl4(CN)2(M = Mn,Fe,Co,Ni)
  • 发蓝色磷光的阴离子铱配合物。

象形图

Skull and crossbonesEnvironment

警示用语:

Danger

危险分类

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1

补充剂危害

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Anhydrous tetrabutylammonium fluoride
Sun H and DiMagno SG
Journal of the American Chemical Society, 127(7), 2050-2051 (2005)
[ReCl4 (CN) 2] 2-: A High Magnetic Anisotropy Building Unit Giving Rise to the Single-Chain Magnets (DMF) 4MReCl4 (CN) 2 (M= Mn, Fe, Co, Ni)
Harris TD, et al.
Journal of the American Chemical Society, 132(11), 3980-3988 (2010)
Synthesis, characterization, and DFT/TD-DFT calculations of highly phosphorescent blue light-emitting anionic iridium complexes
Di Censo D, et al.
Inorganic Chemistry, 47(3), 980-989 (2008)
Colorimetric detection of cyanide with a chromogenic oxazine
Tomasulo M and Raymo FM
Organic Letters, 7(21), 4633-4636 (2005)
A J Chinchalikar et al.
The European physical journal. E, Soft matter, 35(7), 55-55 (2012-07-06)
Clouding is studied by small-angle neutron scattering (SANS) on a charged micellar system of sodium dodecyl sulphate (SDS) and tetrabutylammonium bromide (TBAB) with varying temperature and salt NaCl. We show that the clouding occurs as a result of increase in

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