346276
六氟磷酸四乙氰铜
97%, solid
别名:
四氟化亚铜（乙腈）六氟磷酸盐, 铜（I）四（乙腈）六氟磷酸盐
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关于此项目
线性分子式:
[(CH3CN)4Cu]PF6
化学文摘社编号:
分子量:
372.72
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
六氟磷酸四乙氰铜, 97%
form
solid
SMILES string
[Cu+].CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F
InChI
1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1
InChI key
GNQXUMGHBSAQBV-UHFFFAOYSA-N
assay
97%
mp
160 °C (dec.) (lit.)
reaction suitability
reagent type: catalyst, reagent type: catalyst
core: copper
reaction type: click chemistry
Quality Level
Application
四（乙腈）铜（I）六氟磷酸盐可分别通过芳醛、双甲酮和尿唑或邻苯二甲酰肼的反应，用作合成三唑并[1,2-a]吲唑-1,3,8-三酮和2H-吲唑并[2,1-b]酞嗪-三酮衍生物的催化剂。
它也可以用作铜前体：
它也可以用作铜前体：
- 通过阳离子交换过程，用于形成铜2S/CdS纳米棒结。
- 合成单金属铜大环双喹唑啉配体[Cu（Mabiq）]。
- 制备亚铜络合物[Cu（2-iQBO）（POP）] PF6]；其中2-iQBO = 2-（1′-异喹啉基）苯并恶唑，POP = 双[2-（二苯基膦基）苯基]醚，其可形成发光假多晶型物。
- 用于[Cu（NHC）2] PF6复合物[（NHC = N-杂环卡宾]的合成，其可进一步用于羰基化合物的氢化硅烷化。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Differential conductance (dI/dV) imaging of a heterojunction-nanorod.
Kundu B, et al.
Nanotechnology, 28(9), 095705-095705 (2017)
Structural Characterization and Photochemical Properties of Mono-and Bimetallic Cu-Mabiq Complexes.
Stark HS, et al.
Inorganic Chemistry, 28(9), 095705-095705 (2018)
Synthesis and characterization of [Cu (NHC)2] X complexes: Catalytic and mechanistic studies of hydrosilylation reactions.
Diez-Gonzalez S, et al.
Chemistry?A European Journal , 14(1), 158-168 (2008)
Dinglong Chen et al.
Analytical biochemistry, 497, 27-35 (2016-01-09)
Copper is an essential metal in all organisms. Reliably quantifying and identifying the copper content and oxidation state is crucial, since the information is essential to understanding protein structure and function. Chromophoric ligands, such as Bathocuproine (BC) and its water-soluble
Two luminescent pseudo-polymorphic cuprous complexes with different optical properties: Synthesis, characterization and TD-DFT calculations.
Tao XD, et al.
Polyhedron, 144(9), 36-43 (2018)
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