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形式
liquid
质量水平
反应适用性
reagent type: ligand
reaction type: Arylations
浓度
1.0 M in THF
密度
0.869 g/mL at 25 °C
官能团
phosphine
SMILES字符串
CCP(CC)CC
InChI
1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3
InChI key
RXJKFRMDXUJTEX-UHFFFAOYSA-N
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应用
Catalyst for:
- Regioselective formation of alcohols from hydrocarbonylation of alkenes
- Bronsted acid-assisted synthesis of dihydropyrones from aromatic aldehydes and allenoates
- Silaboration of enynes
- Conversion of phenylacetic acids to phenylacetonitriles of benzonitriles
- Thermal decomposition of platinum and palladium naphthalenediyl
- Asymmetrical Morita-Baylis-Hillman reaction
警示用语:
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Central nervous system, Respiratory system
补充剂危害
WGK
WGK 3
闪点(°F)
-4.0 °F
闪点(°C)
-20 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Chemistry (Weinheim an der Bergstrasse, Germany), 21(37), 13027-13034 (2015-08-01)
Silyl triflates of the form R4-n Si(OTf)n (n=1, 2; OTf=OSO3 CF3 ) are shown to activate carbon dioxide when paired with bulky alkyl-substituted Group 15 bases. Combinations of silyl triflates and 2,2,6,6-tetramethylpiperidine react with CO2 to afford silyl carbamates via a
Physical chemistry chemical physics : PCCP, 17(35), 23041-23051 (2015-08-15)
This work presents the physicochemical characterization of two ionic liquids (ILs) with small phosphonium cations, triethylpenthylphosphonium bis(trifluoromethanesulfonyl)imide ([P2225][Tf2N]) and (2-methoxyethyl)trimethylphosphonium bis(trifluoromethanesulfonyl)imide ([P222(201)][Tf2N]), and their mixtures with Li(+). Properties such as the electrochemical window, density, viscosity and ionic conductivity are presented.
Cancer genomics & proteomics, 12(6), 271-281 (2015-11-07)
Follicular adenoma is a type of benign and encapsulated nodule in the thyroid gland, but some adenomas have the potential to progress to follicular carcinoma. Therefore, it is important to monitor the state and progress of follicular adenoma in the
Proteomics, 15(13), 2358-2368 (2015-03-11)
Chondrosarcoma is the third most common primary bone cancer, requiring surgical resection. However, differentiation of low-grade chondrosarcoma (grade 1) from enchondroma that is benign and only requires regular follow-up is one of the most frequent diagnostic dilemmas facing orthopedic oncologists
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