所有图片(2)
About This Item
线性分子式:
BrMn(CO)5
CAS号:
分子量:
274.89
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
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质量水平
方案
98%
表单
powder or crystals
反应适用性
core: manganese
reagent type: catalyst
储存温度
2-8°C
SMILES字符串
[Mn]Br.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InChI key
OESORJHGSXJTKX-UHFFFAOYSA-M
一般描述
Bromopentacarbonylmanganese(I)is an organomanganese compound with a central manganese atom at its core,enclosed by five carbon monoxide ligands and one bromine atom. It is commonlyused as a reagent in organic synthesis, particularly in carbonylationreactions. It is also used as a precursor for the preparation of various manganesecomplexes.
应用
溴五羰基锰(I)可以作为
- ：前体，用于合成锰复合物[Mn(CO)5H]，然后作为催化剂用于将乙酰丙酸（LA）还原为甲基四氢呋喃（MTHF），将LA还原胺化为N-取代吡啶。
- 一种前体，用于制备含双功能配体的Mn(I)复合物，该复合物用作催化剂，以2-丙醇为氢供体进行各种酮和亚胺的转移氢化反应。
- 选择性C2-H活化反应的催化剂。
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Miguel N Pinto et al.
Journal of controlled release : official journal of the Controlled Release Society, 264, 192-202 (2017-09-04)
The gaseous signaling molecule carbon monoxide (CO) has recently been recognized for its wide range of physiological activity as well as its antineoplastic properties. However, site-specific delivery of this noxious gas presents a major challenge in hospital settings. In this
Felipe López-Saucedo et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 156, 108983-108983 (2019-11-25)
We report on the synthesis of new manganese carbonyls-based materials prepared using gamma-rays radiation (at doses of 10 and 40 kGy) as energy source. Characterization was achieved using nuclear magnetic resonance, infrared spectroscopy, elemental analysis, single-crystal X-ray diffraction, differential scan calorimetry
Ken T Ngo et al.
Journal of the American Chemical Society, 139(7), 2604-2618 (2017-01-25)
Electrocatalytic reduction of CO
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