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Merck
CN
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文件

341622

Sigma-Aldrich

五羰基溴化锰(I)

98%

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别名:
溴化五羟基合锰, 溴化五羟基合锰(I)
线性分子式:
BrMn(CO)5
CAS号:
14516-54-2
分子量:
274.89
EC 号:
238-522-8
MDL编号:
MFCD00049806
UNSPSC代码:
12352300
PubChem化学物质编号:
24860973
NACRES:
NA.23

质量水平

100

检测方案

98%

形式

powder or crystals

反应适用性

core: manganese
reagent type: catalyst

储存温度

2-8°C

SMILES字符串

[Mn]Br.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1

InChI key

OESORJHGSXJTKX-UHFFFAOYSA-M

相关类别

应用

Bromopentacarbonylmanganese(I) can be used as:
  • A precursor to synthesize manganese complex, [Mn(CO)5H], which was then used as a catalyst in the reduction of levulinic acid (LA) to methyltetrahydrofuran (MTHF) and the reductive amination of LA to N-substituted pyrrolidines.
  • A precursor to prepare Mn(I) complexes bearing bifunctional ligands, which are used as catalysts for the transfer-hydrogenation of various ketones and imines using 2-propanol as the hydrogen donor.
  • A catalyst in the selective C2-H activation reactions.


象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H302 + H312 + H332

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Miguel N Pinto et al.
Journal of controlled release : official journal of the Controlled Release Society, 264, 192-202 (2017-09-04)
The gaseous signaling molecule carbon monoxide (CO) has recently been recognized for its wide range of physiological activity as well as its antineoplastic properties. However, site-specific delivery of this noxious gas presents a major challenge in hospital settings. In this
Felipe López-Saucedo et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 156, 108983-108983 (2019-11-25)
We report on the synthesis of new manganese carbonyls-based materials prepared using gamma-rays radiation (at doses of 10 and 40 kGy) as energy source. Characterization was achieved using nuclear magnetic resonance, infrared spectroscopy, elemental analysis, single-crystal X-ray diffraction, differential scan calorimetry
Ken T Ngo et al.
Journal of the American Chemical Society, 139(7), 2604-2618 (2017-01-25)
Electrocatalytic reduction of CO

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