341622
五羰基溴化锰(I)
98%
别名:
溴化五羟基合锰, 溴化五羟基合锰(I)
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关于此项目
线性分子式:
BrMn(CO)5
化学文摘社编号:
分子量:
274.89
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
238-522-8
MDL number:
产品名称
五羰基溴化锰(I), 98%
InChI key
OESORJHGSXJTKX-UHFFFAOYSA-M
InChI
1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
SMILES string
[Mn]Br.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
assay
98%
form
powder or crystals
reaction suitability
core: manganese
reagent type: catalyst
storage temp.
2-8°C
Quality Level
Application
溴五羰基锰(I)可以作为
- ：前体，用于合成锰复合物[Mn(CO)5H]，然后作为催化剂用于将乙酰丙酸（LA）还原为甲基四氢呋喃（MTHF），将LA还原胺化为N-取代吡啶。
- 一种前体，用于制备含双功能配体的Mn(I)复合物，该复合物用作催化剂，以2-丙醇为氢供体进行各种酮和亚胺的转移氢化反应。
- 选择性C2-H活化反应的催化剂。
General description
五羰基溴化锰是有机锰化合物，锰原子位于中心核，四周围绕着5个一氧化碳配体和1个溴原子。常用作有机合成反应剂，尤其是羰基化反应。也可作为前体制备各种锰复合物。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Miguel N Pinto et al.
Journal of controlled release : official journal of the Controlled Release Society, 264, 192-202 (2017-09-04)
The gaseous signaling molecule carbon monoxide (CO) has recently been recognized for its wide range of physiological activity as well as its antineoplastic properties. However, site-specific delivery of this noxious gas presents a major challenge in hospital settings. In this
Felipe López-Saucedo et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 156, 108983-108983 (2019-11-25)
We report on the synthesis of new manganese carbonyls-based materials prepared using gamma-rays radiation (at doses of 10 and 40 kGy) as energy source. Characterization was achieved using nuclear magnetic resonance, infrared spectroscopy, elemental analysis, single-crystal X-ray diffraction, differential scan calorimetry
Ken T Ngo et al.
Journal of the American Chemical Society, 139(7), 2604-2618 (2017-01-25)
Electrocatalytic reduction of CO
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