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339652

轮环藤宁

Name: 轮环藤宁
Brand: ALDRICH
Price: 9609.75 CNY

97%

别名:

1,4,7,10-四氮环十二烷

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100 MG

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100 MG

¥9,609.75

About This Item

经验公式（希尔记法）:

C₈H₂₀N₄

CAS号:

294-90-6

分子量:

172.27

Beilstein:

606114

MDL编号:

MFCD00066281

UNSPSC代码:

12162002

PubChem化学物质编号:

24860658

NACRES:

NA.23

¥9,609.75

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此商品	684449	684430	684465
684457 [6,6]-苯基 C ₆₁ 丁酸甲酯	684449 [6,6]-苯基 C ₆₁ 丁酸甲酯	684430 [6,6]-苯基 C ₆₁ 丁酸甲酯	684465 [6,6]-苯基 C₇₁ 丁酸甲酯，异构体混合物
assay >99.9%	assay >99.5%	assay >99%	assay 99%
semiconductor properties N-type (mobility=0.21 cm²/V·s)	semiconductor properties N-type (mobility=0.21 cm²/V·s)	semiconductor properties N-type (mobility=0.21 cm²/V·s)	semiconductor properties N-type (mobility=0.1 cm²/V·s)
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 100
form solid	form solid	form powder	form powder
description functionalized fullerene	description functionalized fullerene	description functionalized fullerene	description -
solubility chlorobenzene: soluble	solubility -	solubility chlorobenzene: soluble, organic solvents: soluble, toluene: soluble	solubility chlorobenzene: soluble, organic solvents: soluble, toluene: soluble

一般描述

轮环藤宁是一种微环四胺（microcyclic tetramine），可用作与表面金属阳离子形成配位键的配体。它可用作合成前体。它可以通过二硫代草酰胺与过量溴乙烷的S-烷基化反应来制备。[1][2][3]

应用

轮环藤宁是一种氮杂环（azamocrocycle），可用于开发检测金属离子的荧光纳米传感器。[4]

象形图

GHS06,GHS05,GHS09

警示用语：

Danger

危险声明

H302,H311,H314,H410

预防措施声明

P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338

危险分类

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

技术规格说明书

历史批次信息供参考:

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A new synthesis of cyclen (1, 4, 7, 10-tetraazacyclododecane)

Weisman GR and Reed DP

The Journal of Organic Chemistry, 61(15), 5186-5187 (1996)

A Ln(III)-3-hydroxypyridine pH responsive probe optimized by DFT.

Michael A Caldwell et al.

RSC advances, 10(15), 8994-8999 (2020-04-11)

Differences in tissue pH can be diagnostic of cancer and other conditions that shift cell metabolism. Paramagnetic probes are promising tools for pH mapping in vivo using magnetic resonance spectroscopy (MRS) as they provide uniquely shifted MR signals that change

Synthesis of luminescent homo-dinuclear cationic lanthanide cyclen complexes bearing amide pendant arms through the use of copper catalysed (1,3-Huisgen, CuAAC) click chemistry.

Jennifer K Molloy et al.

Organic & biomolecular chemistry, 10(2), 314-322 (2011-11-11)

The design and synthesis of dinuclear-lanthanide complexes possessing triazole-based bridges, formed by using copper catalysed 1,3-cycloaddition reactions between heptadentate alkyne functionalised cyclen europium or terbium complexes and di-azides (CuAAC reactions), are described. While this click reaction worked well for the

Selective hydrolysis of phosphate monoester by a supramolecular phosphatase formed by the self-assembly of a bis(Zn(2+)-cyclen) complex, cyanuric acid, and copper in an aqueous solution (cyclen = 1,4,7,10-tetraazacyclododecane).

Mohd Zulkefeli et al.

Inorganic chemistry, 50(20), 10113-10123 (2011-09-23)

In Nature, organized nanoscale structures such as proteins and enzymes are formed in aqueous media via intermolecular interactions between multicomponents. Supramolecular and self-assembling strategies provide versatile methods for the construction of artificial chemical architectures for controlling reaction rates and the

11B NMR sensing of d-block metal ions in vitro and in cells based on the carbon-boron bond cleavage of phenylboronic acid-pendant cyclen (cyclen = 1,4,7,10-tetraazacyclododecane).

Masanori Kitamura et al.

Inorganic chemistry, 50(22), 11568-11580 (2011-10-21)

Noninvasive magnetic resonance imaging (MRI) including the "chemical shift imaging (CSI)" technique based on (1)H NMR signals is a powerful method for the in vivo imaging of intracellular molecules and for monitoring various biological events. However, it has the drawback

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