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Merck
CN
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文件

337455

Sigma-Aldrich

1,5-环辛二烯双(甲基联苯基磷化氢)铱六氟磷酸盐

97%

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所有图片(1)
别名:
[Ir(PMePh2)2COD]+ PF6-, [Ir(cod)(PPh2Me)2]PF6, {Ir(COD)[PCH3(C6H5)2]2}PF6
经验公式（希尔记法）:
C34H38F6IrP3
CAS号:
38465-86-0
分子量:
845.79
MDL编号:
MFCD00064800
UNSPSC代码:
12161600
PubChem化学物质编号:
24860482
NACRES:
NA.22

质量水平

100

检测方案

97%

反应适用性

core: iridium
reagent type: catalyst

mp

224 °C (dec.) (lit.)

SMILES字符串

[Ir+].F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.CP(c2ccccc2)c3ccccc3.CP(c4ccccc4)c5ccccc5

InChI

1S/2C13H13P.C8H12.F6P.Ir/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2,3,4,5)6;/h2*2-11H,1H3;1-2,7-8H,3-6H2;;/q;;;-1;+1/b;;2-1-,8-7-;;

InChI key

LXKHQEQLBSJJCO-JXNOXZOESA-N

相关类别

应用

(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh2Me)2]PF6, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH2(solv)2(PPh2Me)2]PF6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Intramolecular allylboration of γ-(?-formylalkoxy) allylboronates for syntheses of trans-or cis-2-(ethenyl) tetrahydropyran-3-ol and 2-(ethenyl) oxepan-3-ol.
Yamamoto Y, et al.
Tetrahedron, 59(4), 537-542 (2003)
Stereoselective Isomerization of Unsymmetrical Diallyl Ethers to Allyl (E)-Vinyl Ethers by a Cationic Iridium Catalyst.
Yamamoto Y, et al.
Synthetic Communications, 30(13), 2383-2391 (2000)
Synthesis of Chiral Esters of (E)-3-(Silyloxy)-2-propenylboronic Acid via the Iridium-Catalyzed Isomerization of the Double Bond.
Yamamoto Y, et al.
The Journal of Organic Chemistry, 64(1), 296-298 (1999)
Paulsen, H.; Adermann, K.
Carbohydrate Research, 175, 163-163 (1988)
Isomerisation of allyl ethers catalysed by the cationic iridium complex [Ir (cyclo-octa-1, 5-diene)(PMePh 2) 2] PF 6. A highly stereoselective route to trans-propenyl ethers.
Baudry D, et al.
Journal of the Chemical Society. Chemical Communications, (16), 694-695 (1978)
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