蒸汽压
5.19 psi ( 20 °C)
质量水平
检测方案
99%
形式
liquid
折射率
n20/D 1.3 (lit.)
bp
45 °C (lit.)
密度
1.693 g/mL at 25 °C (lit.)
SMILES字符串
OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F
InChI
1S/C4HF9O/c5-2(6,7)1(14,3(8,9)10)4(11,12)13/h14H
InChI key
XZNOAVNRSFURIR-UHFFFAOYSA-N
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一般描述
高氟叔丁醇也称为全氟叔丁醇和 ′人造血液′。
应用
高氟叔丁醇可用作制备适当的双(聚氟烷氧基甲基)甲醇及其对应的甲磺酸盐的前体。
警示用语:
Danger
危险分类
Acute Tox. 3 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves
Greener fluorous chemistry: Convenient preparation of new types of 'CF< sub> 3</sub>-rich'secondary alkyl mesylates and their use for the synthesis of azides, amines, imidazoles and imidazolium salts
Journal of Fluorine Chemistry, 131(12), 1368-1376 (2010)
Cyclization and rearrangement products from coupling reactions between terminal< i> o</i>-alkynylphenols or< i> o</i>-ethynyl (hydroxymethyl) benzene and 6-halopurines.
Tetrahedron, 62(25), 6121-6131 (2006)
Organic letters, 21(13), 5206-5210 (2019-06-30)
A highly efficient method to incorporate the nonafluoro- tert-butoxy group into various arenes is developed. This C-O cross-coupling reaction proceeds smoothly in the absence of transition-metal catalyst with good functional group tolerance and scalability. In comparison with the conventional approach
Macromolecular rapid communications, 42(3), e2000482-e2000482 (2020-10-14)
Polyurethane hydrogels are attractive materials finding multiple applications in various sectors of prime importance; however, they are still prepared by the toxic isocyanate chemistry. Herein the facile and direct preparation in water at room temperature of a large palette of
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