331023
高氟叔丁醇
99%
别名:
1,1,1,3,3,3-六氟-2-三氟甲基-2-丙醇, 全氟叔丁醇
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线性分子式:
(CF3)3COH
化学文摘社编号:
分子量:
236.04
UNSPSC Code:
12352100
NACRES:
NA.05
PubChem Substance ID:
EC Number:
219-157-3
Beilstein/REAXYS Number:
1841640
MDL number:
产品名称
高氟叔丁醇, 99%
InChI key
XZNOAVNRSFURIR-UHFFFAOYSA-N
InChI
1S/C4HF9O/c5-2(6,7)1(14,3(8,9)10)4(11,12)13/h14H
SMILES string
OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F
vapor pressure
5.19 psi ( 20 °C)
assay
99%
form
liquid
refractive index
n20/D 1.3 (lit.)
bp
45 °C (lit.)
density
1.693 g/mL at 25 °C (lit.)
functional group
fluoro
hydroxyl
Quality Level
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Application
高氟叔丁醇可用作制备适当的双（聚氟烷氧基甲基）甲醇及其对应的甲磺酸盐的前体。
General description
高氟叔丁醇也称为全氟叔丁醇和 ′人造血液′。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves
Huan Meng et al.
Organic letters, 21(13), 5206-5210 (2019-06-30)
A highly efficient method to incorporate the nonafluoro- tert-butoxy group into various arenes is developed. This C-O cross-coupling reaction proceeds smoothly in the absence of transition-metal catalyst with good functional group tolerance and scalability. In comparison with the conventional approach
Cyclization and rearrangement products from coupling reactions between terminal< i> o</i>-alkynylphenols or< i> o</i>-ethynyl (hydroxymethyl) benzene and 6-halopurines.
Berg TC, et al.
Tetrahedron, 62(25), 6121-6131 (2006)
Greener fluorous chemistry: Convenient preparation of new types of 'CF< sub> 3</sub>-rich'secondary alkyl mesylates and their use for the synthesis of azides, amines, imidazoles and imidazolium salts
Nemes A, et al.
Journal of Fluorine Chemistry, 131(12), 1368-1376 (2010)
Maxime Bourguignon et al.
Macromolecular rapid communications, 42(3), e2000482-e2000482 (2020-10-14)
Polyurethane hydrogels are attractive materials finding multiple applications in various sectors of prime importance; however, they are still prepared by the toxic isocyanate chemistry. Herein the facile and direct preparation in water at room temperature of a large palette of
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