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Merck
CN

326712

钌黑

greener alternative

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经验公式(希尔记法):
Ru
化学文摘社编号:
分子量:
101.07
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141739
EC Number:
231-127-1
MDL number:
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InChI key

KJTLSVCANCCWHF-UHFFFAOYSA-N

InChI

1S/Ru

SMILES string

[Ru]

assay

≥98%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

resistivity

7.1 μΩ-cm, 0°C

surface area

17-26 m2/g

bp

3900 °C (lit.)

mp

2310 °C (lit.)

density

12.45 g/cm3 (lit.)

greener alternative category

Quality Level

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Application

Ru based complexes may be used in the synthesis of anticancer drugs. Ru complexes in conjunction with magnesium may be used in the atom transfer radical addition (ATRA) and cyclization (ATRC) reactions.
Ru may be used as a catalyst in the following reactions;
  • oxidative coupling of indoles and pyrroles with several alkenes
  • arylations reactions.

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Packaging

Packaged in glass bottles

存储类别

4.1B - Flammable solid hazardous materials

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Bin Li et al.
The Journal of organic chemistry, 78(18), 9345-9353 (2013-09-13)
An efficient ruthenium-catalyzed oxidative coupling of indoles and pyrroles with various alkenes at the C2-position assisted by employing the N,N-dimethylcarbamoyl moiety as a directing group is reported. The catalytic reaction proceeds in an excellent regio- and stereoselective manner.
Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes.
Dipankar Srimani et al.
Angewandte Chemie (International ed. in English), 52(14), 4012-4015 (2013-03-08)
Rafael E Rodríguez-Lugo et al.
Nature chemistry, 5(4), 342-347 (2013-03-21)
The development of an efficient catalytic process that mimics the enzymatic function of alcohol dehydrogenase is critical for using biomass alcohols for both the production of H2 as a chemical energy carrier and fine chemicals under waste-free conditions. Dehydrogenation of
Lipeng Wu et al.
Journal of the American Chemical Society, 135(10), 3989-3996 (2013-02-20)
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands and triruthenium dodecacarbonyl as catalyst. Both industrially important aliphatic as well as various functionalized olefins react with primary and
M Beye et al.
Physical review letters, 110(18), 186101-186101 (2013-05-21)
We have studied the femtosecond dynamics following optical laser excitation of CO adsorbed on a Ru surface by monitoring changes in the occupied and unoccupied electronic structure using ultrafast soft x-ray absorption and emission. We recently reported [M. Dell'Angela et

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