跳转至内容
Merck
CN
  • Efficient and regioselective ruthenium-catalyzed hydro-aminomethylation of olefins.

Efficient and regioselective ruthenium-catalyzed hydro-aminomethylation of olefins.

Journal of the American Chemical Society (2013-02-20)
Lipeng Wu, Ivana Fleischer, Ralf Jackstell, Matthias Beller
摘要

An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands and triruthenium dodecacarbonyl as catalyst. Both industrially important aliphatic as well as various functionalized olefins react with primary and secondary amines to give the corresponding secondary and tertiary amines generally in high yields (up to 96%) and excellent regioselectivities (n/iso up to 99:1).

材料
货号
品牌
产品描述

Sigma-Aldrich
钌, powder, 99.99% trace metals basis
价格与库存信息目前不能提供
Sigma-Aldrich
钌, powder, −200 mesh, 99.9% trace metals basis
价格与库存信息目前不能提供
Sigma-Aldrich
钌黑
价格与库存信息目前不能提供