所有图片(1)
About This Item
线性分子式:
((CH3)4C2O2)BCH2CH=CH2
CAS号:
分子量:
168.04
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
折射率
n20/D 1.4268 (lit.)
沸点
50-53 °C/5 mmHg (lit.)
密度
0.896 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC1(C)OB(CC=C)OC1(C)C
InChI
1S/C9H17BO2/c1-6-7-10-11-8(2,3)9(4,5)12-10/h6H,1,7H2,2-5H3
InChI key
YMHIEPNFCBNQQU-UHFFFAOYSA-N
一般描述
烯丙基硼酸季戊醇酯在简单酮亚胺的催化烯丙基化反应中被用作亲核试剂。
应用
作为试剂用于以下反应
试剂用于制备
- 钯催化的铃木宫村交叉偶联反应和烯烃复分解
- 分子间自由基加成
- 手性螺二茚二醇（SPINOL）基磷酸催化醛烯丙基化
- 钴催化二烯与烯烃的区域选择性加氢乙烯基化
- 核酸模板能量转移导致光释放反应
- 立体选择性铟催化的Hosomi-Sakurai反应
试剂用于制备
- 环砜羟乙胺作为BACE1抑制剂减少淀粉样蛋白β-肽
- 碳烯碘化钌与银羧酸盐的金属转移，得到碳氢活化的钌碳烯配合物作为Z选择性烯烃复分解的催化剂
- 烯丙基硼化试剂，用于制备烯丙醇和高烯丙基胺。
警示用语：
Warning
危险声明
危险分类
Flam. Liq. 3
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
114.8 °F - closed cup
闪点(°C)
46 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Sambasivarao Kotha et al.
The Journal of organic chemistry, 77(1), 482-489 (2011-12-02)
Palladium-catalyzed Suzuki-Miyaura (SM) cross-coupling reaction with allylboronic acid pinacol ester and titanium assisted cross-metathesis (CM)/ring-closing metathesis (RCM) cascade has been used to synthesize macrocyclic cyclophane derivatives.
Organic Syntheses, 83, 170-170 (2006)
Heinrich Rueeger et al.
Journal of medicinal chemistry, 55(7), 3364-3386 (2012-03-03)
Structure-based design of a series of cyclic hydroxyethylamine BACE1 inhibitors allowed the rational incorporation of prime- and nonprime-side fragments to a central core template without any amide functionality. The core scaffold selection and the structure-activity relationship development were supported by
Catalytic enantioselective allylation of ketoimines
Reiko W et al.
Journal of the American Chemical Society, 128, 7687-7691 (2006)
Manuel Röthlingshöfer et al.
Journal of the American Chemical Society, 133(45), 18110-18113 (2011-10-19)
The photocleavage of a nitrobenzyl-type linker (NPPOC) at 405 nm wavelength was enabled by nucleic acid-templated energy transfer from a sensitizer (thioxanthenone) to the linker. This strategy was used to release profluorescent rhodamine, which facilitated monitoring of the reaction via
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