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Merck
CN

302937

Sigma-Aldrich

全氟(甲基环己烷)

technical grade, 90%

别名:

十一氟(三氟甲基)环己烷, 全氟甲基环己烷

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About This Item

线性分子式:
C6F11CF3
CAS号:
分子量:
350.05
Beilstein:
1915981
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

等级

technical grade

质量水平

方案

90%

表单

liquid

折射率

n17/D 1.285 (lit.)

沸点

76 °C (lit.)

密度

1.787 g/mL at 25 °C (lit.)

官能团

fluoro

SMILES字符串

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F

InChI

1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12

InChI key

QIROQPWSJUXOJC-UHFFFAOYSA-N

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一般描述

氯仿和全氟(甲基环己烷)的混合物可用作“氟”双相反应的溶剂。已有研究报道了全氟(甲基环己烷)的气相结构。

应用

使用全氟(甲基环己烷)作为溶剂,研究一系列烃和碳氟化合物官能化的烟酸酯的亲氟性。
全氟甲基环己烷可用作:
  • 反应物,用于通过与水中的四丁基碘化铵进行光化学反应合成全氟-2-甲基环己基-1-烯醇化物。
  • 氟溶剂,用于以氟 Grubbs ′二代催化剂通过降冰片烯的开环复分解聚合 (ROMP) 合成聚降冰片烯。

它还可用作溶剂,研究一系列烃和碳氟化合物官能化烟酸酯的亲氟性。

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves


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Development of Highly Active Ring Opening Metathesis Polymerization Catalyst Systems-A New Approach for Green Catalyst Design
Tuba R, et al.
Proceedings, 2011(1), EVO3-EVO3 (2011)
Functionalization of saturated fluorocarbons with and without light
Chen X and Lemal DM
Journal of Fluorine Chemistry, 127(9), 1158-1167 (2006)
Stephanie S Adkins et al.
The journal of physical chemistry. B, 112(15), 4760-4769 (2008-03-28)
The technique of hydrophobic ion pairing was used to solubilize the lipase from Candida rugosa in a fluorinated solvent, perfluoromethylcyclohexane (PFMC), in complex with a perfluoropolyether (PFPE) surfactant, KDP 4606. The enzyme-surfactant complex was determined to have a hydrodynamic diameter
Graeme R Kafka et al.
The journal of physical chemistry. A, 114(41), 11022-11026 (2010-09-30)
When refining structures using gas electron diffraction (GED) data, assumptions are often made in order to reduce the number of required geometrical parameters. Where these relate to light, peripheral atoms there is little effect on the refined heavy-atom structure, which
Miharu Koshino et al.
Ultrasonics sonochemistry, 54, 250-255 (2019-02-05)
We have developed a new emulsion template method for the synthesis of poly(methylmethacrylate) (PMMA) hollow nanoparticles with different sizes. This synthetic method involves sequential ultrasonic irradiation (20 kHz → 500 kHz → 1.6 MHz → 2.4 MHz → 5.0 MHz) for acoustic emulsification of a water-insoluble fluorous solvent such as perfluoromethylcyclohexane (PFMCH) in

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