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质量水平
方案
99%
表单
liquid
折射率
n20/D 1.349 (lit.)
沸点
79-81 °C (lit.)
密度
1.37 g/mL at 25 °C (lit.)
官能团
chloro
ester
fluoro
SMILES字符串
COC(=O)C(F)(F)Cl
InChI
1S/C3H3ClF2O2/c1-8-2(7)3(4,5)6/h1H3
InChI key
AWUPLMYXZJKHEG-UHFFFAOYSA-N
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一般描述
Methyl chlorodifluoroacetate is a trifluoromethylating agent.
应用
Methyl chlorodifluoroacetate was used in preparation of 2,2-difluoro-3-hydroxyesters and gem-difluorocyclopropane.
警示用语：
Danger
危险声明
危险分类
Flam. Liq. 2 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
66.2 °F - closed cup
闪点(°C)
19 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Methyl chlorodifluoroacetate a convenient trifluoromethylating agent.
De-Bao S, et al.
Tetrahedron Letters, 32(52), 7689-7690 (1991)
Preparation of gem-difluorocyclopropanes via decomposition of methyl chlorodifluoroacetate by alkali metal halides.
Wheaton GA and Burton DJ.
Journal of Fluorine Chemistry, 9(1), 25-44 (1977)
Electrochemical, nickel-catalyzed Reformatsky reaction with methyl chlorodifluoroacetate
Mcharek S, et al.
Journal of Organometallic Chemistry, 401(1), 211-215 (1991)
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