298980
邻甲苯基溴化镁 溶液
2.0 M in diethyl ether
别名:
2-Methylphenylmagnesium bromide, 2-Tolylmagnesium bromide, o-Methylphenylmagnesium bromide, Bromo(2-methylphenyl)magnesium, Bromo-o-tolylmagnesium
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所有图片(1)
About This Item
线性分子式:
CH3C6H4MgBr
CAS号:
分子量:
195.34
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
反应适用性
reaction type: Grignard Reaction
浓度
2.0 M in diethyl ether
密度
1.013 g/mL at 25 °C
SMILES字符串
Cc1ccccc1[Mg]Br
InChI
1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h2-5H,1H3;1H;/q;;+1/p-1
InChI key
DVXDIGKNJYSMFM-UHFFFAOYSA-M
应用
o-Tolylmagnesium bromide solution can be used to prepare:
- An iridium(I) mesityl complex named Ir(o-tolyl)(CO)(dppe).
- 4-(2-Methylphenyl)-4-oxobutanoic acid, a key intermediate for the synthesis of M1 muscarinic selective agonist AC-42 derivatives.
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
靶器官
Central nervous system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
-40.0 °F
闪点(°C)
-40 °C
法规信息
新产品
Fluorescent derivatives of AC-42 to probe bitopic orthosteric/allosteric binding mechanisms on muscarinic M1 receptors
Daval SB, et al.
Journal of Medicinal Chemistry, 55(5), 2125-2143 (2012)
Chihiro Tsukano et al.
Chemical & pharmaceutical bulletin, 65(12), 1167-1174 (2017-12-05)
Tetrahydrobiphenylene consists of cyclobutene fused with benzene and cyclohexene rings. In this paper, a direct method for synthesizing tetrahydrobiphenylenes based on a palladium (Pd)(0)-catalyzed C(sp
Synthesis and Reactivity of the Iridium (I) Mesityl Complex Ir (CO)(mes)(dppe). Oxidative Addition and Ligand Activation Reactions
Cleary BP and Eisenberg R
Journal of the American Chemical Society, 117(12), 3510-3521 (1995)
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