推荐产品
质量水平
方案
98%
折射率
n20/D 1.387 (lit.)
沸点
112 °C/700 mmHg (lit.)
密度
1.583 g/mL at 25 °C (lit.)
官能团
bromo
ester
fluoro
SMILES字符串
CCOC(=O)C(F)(F)Br
InChI
1S/C4H5BrF2O2/c1-2-9-3(8)4(5,6)7/h2H2,1H3
InChI key
IRSJDVYTJUCXRV-UHFFFAOYSA-N
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应用
溴二氟乙酸乙酯已用于制备：
- 取代的2′-吡啶基二氟乙酸乙酯
- 4-烷氧基甲基-和4-芳氧基甲基-3,3-二氟哌啶
- α,α-二氟-β-内酰胺类
- 单氟甲基化和二氟甲基化的菲啶衍生物
警示用语：
Danger
危险声明
危险分类
Flam. Liq. 2 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
69.8 °F - closed cup
闪点(°C)
21 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Atsushi Tarui et al.
Organic & biomolecular chemistry, 12(33), 6484-6489 (2014-07-16)
A practical and highly enantioselective Reformatsky reaction of ethyl bromodifluoroacetate with imines using a cheap and commercially available amino alcohol ligand is described. A variety of α,α-difluoro-β-lactams were obtained in up to 74% yield with high enantioselectivity in excess of
Riccardo Surmont et al.
The Journal of organic chemistry, 75(3), 929-932 (2010-01-07)
Synthetic strategies toward 4-substituted 3,3-difluoropiperidines were evaluated. 4-Alkoxymethyl- and 4-aryloxymethyl-3,3-difluoropiperidines were synthesized via 1,4-addition of ethyl bromodifluoroacetate to 3-substituted acrylonitriles in the presence of copper powder, followed by borane reduction of the cyano substituent, lactamization, and reduction of the lactam.
Xiaoyang Sun et al.
Organic letters, 16(11), 2938-2941 (2014-05-23)
A practical and unified strategy has been described for the preparation of mono- and difluoromethylated phenanthridine derivatives using a visible-light-promoted alkylation and decarboxylation sequence from biphenyl isocyanides with ethyl bromofluoroacetate (EBFA) or ethyl bromodifluoroacetate (EBDFA). These reactions could be carried
Copper-mediated reaction of 2-halopyridines with ethyl bromodifluoroacetate.
Ashwood MS, et al.
Tetrahedron Letters, 43(50), 9271-9273 (2002)
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