推荐产品
质量水平
反应适用性
reaction type: Grignard Reaction
浓度
2.0 M in diethyl ether
密度
0.947 g/mL at 25 °C
SMILES字符串
CCCCC[Mg]Br
InChI
1S/C5H11.BrH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1
InChI key
ZXWGTPYWPZGZPT-UHFFFAOYSA-M
应用
Pentylmagnesium bromide solution is a Grignard reagent that can be used in the preparation of:
It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.
- Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides.
- Hydroxypiperidinones via the addition-cyclization-deprotection process of aldimines.
It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
靶器官
Central nervous system
补充剂危害
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
闪点(°F)
-40.0 °F - closed cup
闪点(°C)
-40 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
A six-step asymmetric synthesis of (+)-hyperaspine
Comins DL and Sahn JJ
Organic Letters, 7(23), 5227-5228 (2005)
Ni-or Cu-catalyzed cross-coupling reaction of alkyl fluorides with Grignard reagents
Terao J, et al.
Journal of the American Chemical Society, 125(19), 5646-5647 (2003)
Alkylation of Si surfaces using a two-step halogenation/Grignard route
Bansal A, et al.
Journal of the American Chemical Society, 118(30), 7225-7226 (1996)
Muhammad Waqar Ashraf et al.
Bulletin of environmental contamination and toxicology, 98(6), 811-816 (2017-04-14)
In the present work, data on the levels of hazardous Organotin compounds in eight commercially important fish species, caught from Arabian Gulf, has been reported. Highest levels of tributyltin (TBT) (98.5 ng/g dry weight) were detected in Epinephelus Tauvina whereas minimum
Diastereoconvergent Synthesis of trans-5-Hydroxy-6-Substituted-2-Piperidinones by Addition-Cyclization-Deprotection Process
Si Chang-Mei, et al.
Organic Letters, 16(16), 4328-4331 (2014)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门