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质量水平
反应适用性
reaction type: Grignard Reaction
浓度
2.0 M in diethyl ether
密度
0.947 g/mL at 25 °C
SMILES字符串
CCCCC[Mg]Br
InChI
1S/C5H11.BrH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1
InChI key
ZXWGTPYWPZGZPT-UHFFFAOYSA-M
应用
Pentylmagnesium bromide solution is a Grignard reagent that can be used in the preparation of:
It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.
- Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides.
- Hydroxypiperidinones via the addition-cyclization-deprotection process of aldimines.
It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.
警示用语:
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
靶器官
Central nervous system
补充剂危害
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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Diastereoconvergent Synthesis of trans-5-Hydroxy-6-Substituted-2-Piperidinones by Addition-Cyclization-Deprotection Process
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Alkylation of Si surfaces using a two-step halogenation/Grignard route
Journal of the American Chemical Society, 118(30), 7225-7226 (1996)
Ni-or Cu-catalyzed cross-coupling reaction of alkyl fluorides with Grignard reagents
Journal of the American Chemical Society, 125(19), 5646-5647 (2003)
A six-step asymmetric synthesis of (+)-hyperaspine
Organic Letters, 7(23), 5227-5228 (2005)
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