所有图片(1)
About This Item
线性分子式:
Rh(CO)2(C5H7O2)
CAS号:
分子量:
258.03
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
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质量水平
方案
98%
表单
solid
反应适用性
reagent type: catalyst
mp
154-156 °C (lit.)
SMILES字符串
[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh]
InChI
1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
InChI key
BZCAWKOPWNIDOC-FGSKAQBVSA-M
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应用
在分子工程中用于所关注的氟溶氢甲酰化催化剂的原位形成。
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Sol. 1 - Skin Sens. 1
补充剂危害
储存分类代码
4.1B - Flammable solid hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Horvath, I.T. et al.
Journal of the American Chemical Society, 120, 3133-3133 (1998)
Andrei V Pakoulev et al.
The journal of physical chemistry. A, 112(28), 6320-6329 (2008-06-25)
Triply vibrationally enhanced four-wave mixing spectroscopy is employed to observe vibrational coherence transfer between the asymmetric and symmetric CO-stretching modes of rhodium(I) dicarbonyl acetylacetonate (RDC). Coherence transfer is a nonradiative transition of a coherent superposition of quantum states to a
K A Merchant et al.
Physical review letters, 86(17), 3899-3902 (2001-05-01)
2D spectrally resolved ultrafast (<200 fs) IR vibrational echo experiments were performed on Rh(CO)(2)acac [(acetylacetonato)dicarbonylrhodium (I)]. The 2D spectra display features that reflect the 0-1 and 1-2 transitions and the combination band transition of the symmetric (S) and antisymmetric (A)
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