所有图片(1)
About This Item
经验公式（希尔记法）:
C14H6F17N
CAS号:
分子量:
511.18
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
≥95.0% (GC)
表单
solid
mp
42-47 °C
官能团
fluoro
SMILES字符串
NC1=CC=C(C(F)(C(F)(C(F)(C(F)(C(F)(C(F)(C(F)(C(F)(F)F)F)F)F)F)F)F)F)C=C1
InChI
1S/C14H6F17N/c15-7(16,5-1-3-6(32)4-2-5)8(17,18)9(19,20)10(21,22)11(23,24)12(25,26)13(27,28)14(29,30)31/h1-4H,32H2
InChI key
ZQTZVMUNYIDMJV-UHFFFAOYSA-N
应用
4-(Heptadecafluorooctyl)aniline was used in the synthesis of fluorous (S)-pyrrolidine-thiourea bifunctional organocatalyst.
其他说明
用于引入 4-全氟烷基芳基部分的结构单元
警示用语：
Danger
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Lact. - Repr. 1B - STOT RE 1
靶器官
Liver
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
D. Crich et al.
Tetrahedron, 55, 14261-14261 (1999)
N. Yoshino et al.
Bulletin of the Chemical Society of Japan, 65, 2141-2141 (1992)
M. Matsui et al.
Liq. Cryst., 21, 669-669 (1996)
Liang Wang et al.
Synlett : accounts and rapid communications in synthetic organic chemistry, 3(2010), 433-436 (2010-08-19)
A novel fluorous (S)-pyrrolidine-thiourea bifunctional organocatalyst is prepared. The catalyst shows good activity and enantioselectivity for direct α-chlorination of aldehydes using N-chlorosuccinimide (NCS) as the chlorine source. It can be recovered from the reaction mixture by fluorous solid-phase extraction with
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