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Merck
CN
所有图片(1)

文件

285587

Sigma-Aldrich

氟代丙二酸二乙酯

97%

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线性分子式:
FCH(COOC2H5)2
CAS号:
685-88-1
分子量:
178.16
Beilstein:
1775686
EC 号:
211-684-7
MDL编号:
MFCD00009139
UNSPSC代码:
12352100
PubChem化学物质编号:
24857220
NACRES:
NA.22

质量水平

100

检测方案

97%

形式

liquid

折射率

n20/D 1.407 (lit.)

bp

121-122 °C/30 mmHg (lit.)

密度

1.129 g/mL at 25 °C (lit.)

SMILES字符串

CCOC(=O)C(F)C(=O)OCC

InChI

1S/C7H11FO4/c1-3-11-6(9)5(8)7(10)12-4-2/h5H,3-4H2,1-2H3

InChI key

GOWQBFVDZPZZFA-UHFFFAOYSA-N

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相关类别

一般描述

The reaction of diethyl fluoromalonate with electron-poor and electron-rich, sterically hindered and unhindered aryl bromides and chlorides were studied.

应用

The kinetic parameters of diethyl fluoromalonate in hemolysates were used to study carboxylesterase activities in complex systems.

象形图

Corrosion
GHS05

警示用语：

Danger

危险声明

H314

危险分类

Skin Corr. 1B

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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G L Mendz et al.
Archives of biochemistry and biophysics, 305(2), 252-260 (1993-09-01)
Eight fluorinated compounds were tested as putative probes to measure carboxylesterase activity employing 19F nuclear magnetic resonance spectroscopy. The method takes advantage of the sensitivity of fluorine resonances to the changes in the chemical bonding in the covalent structures where
Neil A Beare et al.
The Journal of organic chemistry, 67(2), 541-555 (2002-01-19)
Palladium-catalyzed reactions of aryl bromides and chlorides with two common stabilized carbanions-enolates of dialkyl malonates and alkyl cyanoesters-are reported. An exploration of the scope of these reactions was conducted, and the processes were shown to occur in a general fashion.

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