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质量水平
方案
97%
表单
liquid
折射率
n20/D 1.407 (lit.)
沸点
121-122 °C/30 mmHg (lit.)
密度
1.129 g/mL at 25 °C (lit.)
官能团
ester
fluoro
SMILES字符串
CCOC(=O)C(F)C(=O)OCC
InChI
1S/C7H11FO4/c1-3-11-6(9)5(8)7(10)12-4-2/h5H,3-4H2,1-2H3
InChI key
GOWQBFVDZPZZFA-UHFFFAOYSA-N
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一般描述
The reaction of diethyl fluoromalonate with electron-poor and electron-rich, sterically hindered and unhindered aryl bromides and chlorides were studied.
应用
The kinetic parameters of diethyl fluoromalonate in hemolysates were used to study carboxylesterase activities in complex systems.
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
143.6 °F - closed cup
闪点(°C)
62 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
G L Mendz et al.
Archives of biochemistry and biophysics, 305(2), 252-260 (1993-09-01)
Eight fluorinated compounds were tested as putative probes to measure carboxylesterase activity employing 19F nuclear magnetic resonance spectroscopy. The method takes advantage of the sensitivity of fluorine resonances to the changes in the chemical bonding in the covalent structures where
Neil A Beare et al.
The Journal of organic chemistry, 67(2), 541-555 (2002-01-19)
Palladium-catalyzed reactions of aryl bromides and chlorides with two common stabilized carbanions-enolates of dialkyl malonates and alkyl cyanoesters-are reported. An exploration of the scope of these reactions was conducted, and the processes were shown to occur in a general fashion.
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