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Merck
CN

283657

Sigma-Aldrich

乙酰丙酮镍(II)

95%

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别名:
2,4-戊二酮 镍(II) 衍生物, Ni(acac)2
线性分子式:
Ni(C5H7O2)2
CAS号:
分子量:
256.91
Beilstein:
4157970
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

95%

形式

solid

反应适用性

core: nickel
reagent type: catalyst

mp

230 °C (dec.) (lit.)

SMILES字符串

CC(=O)\C=C(\C)O[Ni]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Ni/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChI key

BMGNSKKZFQMGDH-FDGPNNRMSA-L

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一般描述

Nickel(II) acetylacetonate, known as bis(acetylacetonato)nickel(II) or Ni(acac)2, is a blue-green crystalline compound soluble in water. It finds application in catalysis, materials synthesis, and organic chemistry, playing a crucial role as a catalyst in various reactions and serving as an important precursor for the development of nickel-based nanomaterials and catalysts used in industrial processes and organic transformations.

应用

Nickel(II) acetylacetonate can be:   
  • Used as a precursor to synthesize Ni-based nanomaterials such as NiO/C nanocomposite and crystalline NiO nanoparticles via different synthetic methods like non-isothermal decomposition and solvothermal method.,·      
  • Used to prepare Ni catalysts such as Nickel(II) complexes, and hierarchical Ni/beta catalysts for various organictransformations.
  • Nickel(II) acetylacetonate has several applications in catalysis: It is used as a catalyst for the polymerization of olefins and transesterification reactions.    
  • Nickel(II) acetylacetonate can be employed as a catalyst to promote Michael additions.

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说明
价格

象形图

Health hazardExclamation mark

警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1A - Muta. 2 - Resp. Sens. 1 - Skin Sens. 1

WGK

WGK 3

闪点(°F)

428.0 °F

闪点(°C)

220 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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The catalytic performance of Pt-based catalysts for oxygen reduction reactions (ORR) can generally be enhanced by constructing high-index exposed facets (HIFs). However, the synthesis of Pt alloyed high-index skins on 1D non-Pt surfaces to further improve Pt utilization and stability
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The phase of nanocrystals has a key role in the modulation of catalytic properties. Uniform and well-crystallized nickel phosphide nanocrystals with controlled phases (Ni5 P4 , Ni2 P, and Ni12 P5 ) and narrow size distributions are synthesized by a
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