质量水平
检测方案
98%
mp
108-110 °C (lit.)
SMILES字符串
Fc1c(F)c(I)c(F)c(F)c1I
InChI
1S/C6F4I2/c7-1-2(8)6(12)4(10)3(9)5(1)11
InChI key
VIXRAZODEODOJF-UHFFFAOYSA-N
一般描述
1,4-二碘四氟苯与两分子烷氧基苯乙烯基吡啶形成三聚物复合物，作为新型卤键液晶元。已报道在90K下对4,4′-二吡啶-N,N′-二氧化物与1,4-二碘四氟苯形成的卤键复合物进行的电子密度研究。
1,4-二碘四氟苯是一种双异位全氟碘苯，用于卤代吡啶盐的共晶化。
1,4-二碘四氟苯是一种双异位全氟碘苯，用于卤代吡啶盐的共晶化。
应用
1,4-二碘四氟苯在与多环芳烃的磷光共晶制备过程中用作卤素键供体。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Mesogenic, trimeric, halogen-bonded complexes from alkoxystilbazoles and 1, 4-diiodotetrafluorobenzene.
<BIG>Bruce DW, et al. </BIG>
New. J. Chem., 32(3), 477-482 (2008)
Halogen and hydrogen bond motifs in ionic cocrystals derived from 3-halopyridinium halogenides and perfluorinated iodobenzenes
Lidija P et al.
Crystal Growth & Design, 21, 6044-6050 (2021)
Jay Quentin et al.
Molecules (Basel, Switzerland), 25(4) (2020-02-23)
The halogen-bond (X-bond) donors 1,3- and 1,4-diiodotetrafluorobenzene (1,3-di-I-tFb and 1,4-di-I-tFb, respectively) form cocrystals with trans-1,2-bis(2-pyridyl)ethylene (2,2'-bpe) assembled by N···I X-bonds. In each cocrystal, 2(1,3-di-I-tFb)·2(2,2'-bpe) and (1,4-di-I-tFb)·(2,2'-bpe), the donor molecules support the C=C bonds of 2,2'-bpe to undergo an intermolecular [2+2]
Jiehao Fu et al.
iScience, 23(3), 100965-100965 (2020-03-22)
Here we introduce a σ-hole-containing volatile solid additive, 1, 4-diiodotetrafluorobenzene (A3), in PM6:Y6-based OSCs. Aside from the appropriate volatility of A3 additive, the synergetic halogen interactions between A3 and photoactive matrix contribute to more condensed and ordered molecular arrangement in
Phosphorescent co-crystal assembled by 1, 4-diiodotetrafluorobenzene with carbazole based on C-Ip halogen bonding.
<BIG>Gao HY, et al. </BIG>
Journal of Materials Chemistry, 22(12), 5336-5343 (2012)
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