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Merck
CN

276685

甲基丙烯酸酐

contains 2,000 ppm topanol A as inhibitor, ≥98%

别名:

Methacrylic acid anhydride

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关于此项目

线性分子式:
[H2C=C(CH3)CO]2O
化学文摘社编号:
分子量:
154.16
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1761982
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InChI

1S/C8H10O3/c1-5(2)7(9)11-8(10)6(3)4/h1,3H2,2,4H3

SMILES string

CC(=C)C(=O)OC(=O)C(C)=C

InChI key

DCUFMVPCXCSVNP-UHFFFAOYSA-N

assay

≥98%

form

liquid

contains

2,000 ppm topanol A as inhibitor

refractive index

n20/D 1.453 (lit.)

bp

87 °C/13 mmHg (lit.)

density

1.035 g/mL at 25 °C (lit.)

Quality Level

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Application

甲基丙烯酸酐可用作合成以下材料的起始物:
  • 通过共聚反应合成甲基丙烯酰化软骨素硫酸盐pH敏感水凝胶。这些水凝胶可用于药物传递系统。
  • 高性能木质素基热固性树脂。
  • 凝胶聚合物电解质,然后与阴极集成以形成高性能锂离子电池。
甲基丙烯酸酐也可用作前体,用于合成生物可再生树脂,应用于复合材料应用。例如,它可用于制备大豆油和丁香酚基树脂体系。该树脂具有较高的热稳定性和良好的机械性能,使其成为拉挤工艺的合适基体。

General description

甲基丙烯酸酐是一种有机化合物,来源于甲基丙烯酸,属于丙烯酸类。它主要用作聚合物的单体,特别是聚(甲基丙烯酸)及其共聚物的生产中。由于其优异的化学和热稳定性,这些聚合物在广泛的行业中应用,包括生物可再生树脂、pH敏感水凝胶、热固性树脂、涂料、胶粘剂和塑料。在甲基丙烯酸酐的聚合过程中,最常用的抑制剂是Topanol A。通常以小量(2000 ppm)添加,以阻止在聚合过程中不良的副反应,确保受控和高质量的聚合物形成。

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 2

flash_point_f

183.2 °F - closed cup

flash_point_c

84 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

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Cyclopolymerization. IV. Structure of polymethacrylic anhydride and kinetics of polymerization of methacrylic anhydride.
Smets G, et al.
Journal of Polymer Science: Part A, General Papers, 2(11), 4825-4834 (1964)
Avathamsa Athirasala et al.
Scientific reports, 7(1), 3323-3323 (2017-06-14)
The requirement for immediate vascularization of engineered dental pulp poses a major hurdle towards successful implementation of pulp regeneration as an effective therapeutic strategy for root canal therapy, especially in adult teeth. Here, we demonstrate a novel strategy to engineer
G Bahcecioglu et al.
Biomaterials, 218, 119361-119361 (2019-07-25)
A PCL/hydrogel construct that would mimic the structural organization, biochemistry and anatomy of meniscus was engineered. The compressive (380 ± 40 kPa) and tensile modulus (18.2 ± 0.9 MPa) of the PCL scaffolds were increased significantly when constructs were printed with a shifted design and circumferential
Notes-Acrylic and Methacrylic Anhydrides.
Brotherton T, et al.
The Journal of Organic Chemistry, 26(4), 1283-1284 (1961)
Kunyu Zhang et al.
Materials science & engineering. C, Materials for biological applications, 103, 109835-109835 (2019-07-28)
Hydrogels are promising soft materials for the delivery of therapeutic cells and cargo molecules. Inspired by mussel adhesion chemistry, hydrogels based on catechol (Cat)-modified polysaccharides have been developed to enhance hydrogel-tissue interactions. However, due to the inevitable side reactions such

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