所有图片(1)
About This Item
线性分子式:
(CH3)2PCH2CH2P(CH3)2
CAS号:
分子量:
150.14
Beilstein:
1732994
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
表单
liquid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率
n20/D 1.507 (lit.)
沸点
180 °C (lit.)
密度
0.9 g/mL at 25 °C (lit.)
官能团
phosphine
SMILES字符串
CP(C)CCP(C)C
InChI
1S/C6H16P2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3
InChI key
ZKWQSBFSGZJNFP-UHFFFAOYSA-N
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一般描述
1,2-双（二甲基膦）乙烷 (dmpe) 是一种多齿膦配体。关于1，2-双（二甲基膦）乙烷的合成方法已有报道。它与 ZrCl 2 反应生成 ZrCl 4 (dmpe) 2 配合物。
应用
1,2-双（二甲基膦）乙烷 (dmpe) 可作为配体用于 顺 芳基甲基 (dmpe) 镍 (II) 配合物的制备。
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
Phosphine-induced reductive elimination from cis-arylmethylnickel (II) complexes having a 1,2-bis(dimethylphosphino) ethane ligand
Komiya S, et al.
Organometallics, 2(10), 1466-1468 (1983)
Beatty RP, et al.
Inorganic Chemistry, 18(11), 3139-3145 (1979)
A convenient synthesis of 1, 2-bis (dichlorophosphino) ethane, 1, 2-bis (dimethylphosphino) ethane and 1,2-bis (diethylphosphino) ethane.
Burt RJ, et al.
Journal of Organometallic Chemistry, 182(2), 203-206 (1979)
M Suwalsky et al.
Biochimica et biophysica acta, 1848(11 Pt A), 2829-2838 (2015-08-25)
Usnic acid (UA) has been associated with chronic diseases through its antioxidant action. Its main target is the cell membrane; however, its effect on that of human erythrocytes has been scarcely investigated. To gain insight into the molecular mechanisms of
Mario Suwalsky et al.
The Journal of membrane biology, 248(4), 683-693 (2015-03-01)
Despite the extended use and well-documented information, there are insufficient reports concerning the effects of propranolol on the structure and functions of cell membranes, particularly those of human erythrocytes. Aimed to better understand the molecular mechanisms of its interactions with
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