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质量水平
检测方案
97%
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率
n20/D 1.588 (lit.)
bp
70 °C/1 mmHg (lit.)
密度
1.536 g/mL at 25 °C (lit.)
官能团
phosphine
SMILES字符串
ClP(Cl)CCP(Cl)Cl
InChI
1S/C2H4Cl4P2/c3-7(4)1-2-8(5)6/h1-2H2
InChI key
SBWAJHLQMFBNIN-UHFFFAOYSA-N
一般描述
1,2-双(二氯磷基)-乙烷是一种有机磷化合物,通常作为前体与有机金属反应合成乙烯桥联双磷烷配体。
应用
1,2-双(二氯磷基)-乙烷可作为前体合成1,2-双(二氯膦酰基)-乙烷(ethylenebis(phosphonic dichloride))。
警示用语:
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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A convenient synthesis of 1, 2-bis (dichlorophosphino) ethane, 1, 2-bis (dimethylphosphino) ethane and 1, 2-bis (diethylphosphino) ethane
Journal of Organometallic Chemistry, 182(2), 203-206 (1979)
ChemSusChem, 12(14), 3278-3285 (2019-04-30)
Methyl formate was produced in one pot through the hydrogenation of CO2 to formic acid/formate followed by an esterification step. The route offers the possibility to integrate renewable energy into the fossil-based chemical value chain. In this work, a phosphine-polymer-anchored
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