InChI key
FFRYUAVNPBUEIC-UHFFFAOYSA-N
InChI
1S/C8H6N2O/c11-8-5-9-6-3-1-2-4-7(6)10-8/h1-5H,(H,10,11)
SMILES string
Oc1cnc2ccccc2n1
assay
99% (HPLC)
mp
271-272 °C (lit.)
Quality Level
General description
Epitaxial crystallization of syndiotactic polypropylene on 2-quinoxalinol yields isochiral form II of syndiotactic polypropylene. 2-Quinoxalinol participates in direct dehydrative cross-coupling of 2-quinoxalinone with p-tolylacetylene via Pd/Cu-catalyzed phosphonium coupling.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Fu-An Kang et al.
Chemical communications (Cambridge, England), 46(8), 1347-1349 (2010-05-08)
The first chemoselective direct dehydrative cross-coupling of tautomerizable heterocycles with alkynes has been achieved via C-H/C-OH bond activations with direct C(sp(2))-C(sp) bond formation, which is in line with ideal synthesis using readily available materials.
Isochiral form II of syndiotactic polypropylene produced by epitaxial crystallization.
Zhang J, et al.
Macromolecules, 34(18), 6261-6267 (2001)
Pramila Menon et al.
Chemosphere, 53(8), 1023-1031 (2003-09-25)
The dissipation of 14C carbaryl in undisturbed soil cores, and of quinalphos (25EC and 20AF) after seed and soil treatments, was investigated under field use conditions, in a semi-arid groundnut field. Residues were analyzed by TLC and HPLC and additionally
Andreas Behrends et al.
Redox report : communications in free radical research, 9(5), 279-288 (2004-12-21)
Toxicity of the pesticide quinalphos may comprise secondary, delayed effects by its main metabolite 2-hydroxyquinoxaline (HQO). We demonstrate that HQO can destroy photocatalytically vitamins C and E, catecholamines, serotonin, melatonin, the melatonin metabolite AMK (N(1)-acetyl-5-methoxykynuramine), and unsubstituted and substituted anthranilic
Sonja Riediger et al.
Environmental toxicology, 22(1), 33-43 (2007-02-14)
The quinalphos metabolite 2-hydroxyquinoxaline (HQO), previously shown to photocatalytically destroy antioxidant vitamins and biogenic amines in vitro, was tested for toxicity in several small aquatic organisms and for mutagenicity in Salmonella typhimurium. In the rotifer Philodina acuticornis, HQO caused the
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