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Merck
CN

260517

Sigma-Aldrich

2-羟基喹喔啉

99% (HPLC)

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经验公式(希尔记法):
C8H6N2O
CAS号:
分子量:
146.15
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

99% (HPLC)

mp

271-272 °C (lit.)

SMILES字符串

Oc1cnc2ccccc2n1

InChI

1S/C8H6N2O/c11-8-5-9-6-3-1-2-4-7(6)10-8/h1-5H,(H,10,11)

InChI key

FFRYUAVNPBUEIC-UHFFFAOYSA-N

一般描述

Epitaxial crystallization of syndiotactic polypropylene on 2-quinoxalinol yields isochiral form II of syndiotactic polypropylene. 2-Quinoxalinol participates in direct dehydrative cross-coupling of 2-quinoxalinone with p-tolylacetylene via Pd/Cu-catalyzed phosphonium coupling.

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Andreas Behrends et al.
Redox report : communications in free radical research, 9(5), 279-288 (2004-12-21)
Toxicity of the pesticide quinalphos may comprise secondary, delayed effects by its main metabolite 2-hydroxyquinoxaline (HQO). We demonstrate that HQO can destroy photocatalytically vitamins C and E, catecholamines, serotonin, melatonin, the melatonin metabolite AMK (N(1)-acetyl-5-methoxykynuramine), and unsubstituted and substituted anthranilic
Pramila Menon et al.
Chemosphere, 53(8), 1023-1031 (2003-09-25)
The dissipation of 14C carbaryl in undisturbed soil cores, and of quinalphos (25EC and 20AF) after seed and soil treatments, was investigated under field use conditions, in a semi-arid groundnut field. Residues were analyzed by TLC and HPLC and additionally
Fu-An Kang et al.
Chemical communications (Cambridge, England), 46(8), 1347-1349 (2010-05-08)
The first chemoselective direct dehydrative cross-coupling of tautomerizable heterocycles with alkynes has been achieved via C-H/C-OH bond activations with direct C(sp(2))-C(sp) bond formation, which is in line with ideal synthesis using readily available materials.
Isochiral form II of syndiotactic polypropylene produced by epitaxial crystallization.
Zhang J, et al.
Macromolecules, 34(18), 6261-6267 (2001)
Sonja Riediger et al.
Environmental toxicology, 22(1), 33-43 (2007-02-14)
The quinalphos metabolite 2-hydroxyquinoxaline (HQO), previously shown to photocatalytically destroy antioxidant vitamins and biogenic amines in vitro, was tested for toxicity in several small aquatic organisms and for mutagenicity in Salmonella typhimurium. In the rotifer Philodina acuticornis, HQO caused the

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