所有图片(1)
别名:
1-Hexylmagnesium bromide, Bromohexylmagnesium, n-hexylmagnesium bromide
线性分子式:
CH3(CH2)5MgBr
CAS号:
分子量:
189.38
Beilstein:
3535624
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
反应适用性
reaction type: Grignard Reaction
浓度
2.0 M in diethyl ether
密度
0.965 g/mL at 25 °C
SMILES字符串
CCCCCC[Mg]Br
InChI
1S/C6H13.BrH.Mg/c1-3-5-6-4-2;;/h1,3-6H2,2H3;1H;/q;;+1/p-1
InChI key
SFXUWNMDTWQSHE-UHFFFAOYSA-M
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一般描述
Hexylmagnesium bromide, also known as n-hexylmagnesium bromide, is a useful organomagnesium compound that is commonly used in organic synthesis. It is typically prepared by reacting magnesium turnings with 1-bromohexane in diethyl ether solvent.
应用
Hexylmagnesium bromide solution can be used as a reagent in addition reactions. It can add to various electrophiles, such as carbonyl compounds, to form alcohols or carboxylic acids. These types of reactions are commonly used for the synthesis of pharmaceuticals, natural products, and other organic compounds. It is also used to reduce certain functional groups, such as ketones, esters, and nitriles, to form alcohols or amines.
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
靶器官
Central nervous system
补充剂危害
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
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