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Merck
CN

252387

Sigma-Aldrich

五氟丙酸酐

99%

别名:

PFPA, 全氟丙酸酐

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About This Item

线性分子式:
(CF3CF2CO)2O
CAS号:
分子量:
310.05
Beilstein:
1806446
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

99%

表单

liquid

沸点

69-70 °C/735 mmHg (lit.)

密度

1.571 g/mL at 25 °C (lit.)

官能团

anhydride
ester
fluoro

SMILES字符串

FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F

InChI

1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16

InChI key

XETRHNFRKCNWAJ-UHFFFAOYSA-N

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应用

五氟丙酸酐:
  • 用于制备酚酸卤代衍生物,需要测定脑脊液中的一些生物重要酸
  • 用作GC-多离子检测法检测未处理大鼠脑内内源性胺1,2,3,4-四氢异喹啉和1-甲基-1,2,3,4-四氢异喹啉的衍生化试剂
  • 用于通过气液相色谱法同时测定大鼠纹状体多巴胺的主要代谢产物

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

补充剂危害

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

M Kohno et al.
Biochemical and biophysical research communications, 140(1), 448-454 (1986-10-15)
This is the first report to identify 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain. The detection was performed by coupled gas chromatography - multiple ion detection, using heptafluorobutyric anhydride and pentafluoropropionic anhydride as derivatizing reagents. These amines
Simultaneous determination of 3,4-dihydroxyphenylacetic acid and homovanillic acid in milligram amounts of rat striatal tissue by gas-liquid chromatography.
E Watson et al.
Life sciences, 15(12), 2167-2178 (1974-12-15)
Derivatization and gas chromatographic determination of some biologically important acids in cerebrospinal fluid.
E Watson et al.
Analytical biochemistry, 59(2), 441-451 (1974-06-01)
J L Villamor et al.
Journal of analytical toxicology, 29(2), 135-139 (2005-05-21)
A new gas chromatography-mass spectrometry method for the simultaneous identification and quantitation of amphetamine (AP), methamphetamine (MA), 3,4-methylenedioxyamphetamine (MDA), 3,4-methylenedioxymethamphetamine (MDMA), and 3,4-methylenedioxyethamphetamine (MDEA) in hair is proposed. Hair was hydrolyzed in 1 M NaOH at 40 degrees C, subjected
E Ballesteros et al.
Analytical chemistry, 65(13), 1773-1778 (1993-07-01)
A new analytical method that combines on-line derivatization-extraction and gas-liquid chromatography for the determination of N-methylcarbamates is reported. The hydrolysis products of N-methylcarbamates (phenols) are derivatized and extracted in a continuous fashion using pentafluoropropionic anhydride (derivatizing reagent) in n-hexane as

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