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质量水平
方案
98%
表单
liquid
折射率
n20/D 1.347 (lit.)
沸点
96-97 °C (lit.)
密度
1.395 g/mL at 25 °C (lit.)
官能团
anhydride
chloro
ester
fluoro
SMILES字符串
FC(F)(Cl)C(=O)OC(=O)C(F)(F)Cl
InChI
1S/C4Cl2F4O3/c5-3(7,8)1(11)13-2(12)4(6,9)10
InChI key
VBJIFLOSOQGDRZ-UHFFFAOYSA-N
一般描述
Photolysis of the vapour of chlorodifluoroacetic anhydride has been studied over the range 19-201°C using 248nm radiation.
应用
Chlorodifluoroacetic anhydride has been used:
- for dual element acetylation tagging derivatization of amines by using microwave sustained helium emission detector
- as derivatization reagent in determination of estrone and 17β-estradiol in hair by GC-MS
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Skin Corr. 1B
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Photochemistry of anhydrides. Part 6.-Photolysis of chlorodifluoroacetic anhydride,(CF 2 ClCO) 2 O.
Watkins PE and Whittle E.
J. Chem. Soc., Faraday, 80(8), 2323-2329 (1984)
Multi-element taggant and dual homolog derivatization concepts in GC/MED.
Hagen DF, et al.
Spectrochimica Acta. Part B: Atomic Spectroscopy, 40(1), 335-347 (1985)
M H Choi et al.
The Analyst, 125(4), 711-714 (2000-07-13)
An efficient procedure is described for the determination of estrone and 17 beta-estradiol in hair by gas chromatography-mass spectrometry (GC-MS). The method involves alkyloxycarbonylation with isobutyl chloroformate (isoBCF) of phenolic hydroxy groups after alkaline digestion of hair samples. The resulting
Courtney T Jollymore-Hughes et al.
Bioorganic & medicinal chemistry, 24(21), 5270-5279 (2016-09-18)
Association of cholinesterase with β-amyloid plaques and tau neurofibrillary tangles in Alzheimer's disease offers an opportunity to detect disease pathology during life. Achieving this requires development of radiolabelled cholinesterase ligands with high enzyme affinity. Various fluorinated acetophenone derivatives bind to
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