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Merck
CN

245275

Sigma-Aldrich

三乙基膦

99%

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别名:
Triethylphosphorus
线性分子式:
(C2H5)3P
CAS号:
分子量:
118.16
Beilstein:
969170
EC 号:
MDL编号:
UNSPSC代码:
12352128
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

99%

形式

liquid

反应适用性

reagent type: ligand
reaction type: Arylations

折射率

n20/D 1.456 (lit.)

bp

127-128 °C (lit.)

密度

0.802 g/mL at 20 °C (lit.)

官能团

phosphine

SMILES字符串

CCP(CC)CC

InChI

1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3

InChI key

RXJKFRMDXUJTEX-UHFFFAOYSA-N

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相关类别

应用

Triethylphosphine is generally used as a ligand in the organometallic chemistry. It can be used in:
  • Synthesis of the tetrahedrally coordinated L3Fe-Nx complex with a terminal nitride group.
  • Synthesis of (PEt3)2Ni(η2-C14H10), a source of the reactive Ni(PEt3)2 moiety.
  • Synthesis of dinuclear rhodium complexes with triethyllphosphane bridges.

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FlameCorrosion

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Danger

危险声明

危险分类

Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B

WGK

WGK 3

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Breaking the Rule: Synthesis and Molecular Structure of Dinuclear Rhodium Complexes with Bridging and Semibridging Trialkylphosphane Ligands.
Pechmann T, et al.
Angewandte Chemie (International Edition in English), 39(21), 3909-3911 (2000)
Unexpected Intermediates and Products in the C? F Bond Activation of Tetrafluorobenzenes with a Bis (triethylphosphine) Nickel Synthon: Direct Evidence of a Rapid and Reversible C? H Bond Activation by Ni (0).
Johnson S A, et al.
Journal of the American Chemical Society, 130(51), 17278-17280 (2008)
A Tetrahedrally Coordinated L3Fe? N x Platform that Accommodates Terminal Nitride (FeIV? N) and Dinitrogen (FeI? N2? FeI) Ligands.
Betley T A and Peters J C
Journal of the American Chemical Society, 126(20), 6252-6254 (2004)
Matthew R Richardson et al.
Proteomics, 9(9), 2468-2483 (2009-04-30)
Although low-density lipoprotein (LDL) plays a predominant role in atherogenesis, the low-density lipoproteome has not been fully characterized. Moreover, alterations from a Western diet, diabetes, and physical inactivity on this proteome have yet to be determined. Accordingly, relative quantification was
Quintin R Sheridan et al.
The journal of physical chemistry. B, 120(46), 11951-11960 (2016-10-27)
A combination of X-ray scattering experiments and molecular dynamics simulations were conducted to investigate the structure of ionic liquids (ILs) which chemically bind CO

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