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Merck
CN

236071

Sigma-Aldrich

N,N′-双(亚水杨基)乙二胺

98%

别名:

N,N′-双水杨醛缩乙二胺, 二亚水杨基乙二胺

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About This Item

线性分子式:
(CH2N=CHC6H4OH)2
CAS号:
分子量:
268.31
Beilstein:
535296
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

98%

mp

127-128 °C (lit.)

溶解性

water: insoluble(lit.)

官能团

amine
imine

SMILES字符串

Oc1ccccc1\C=N\CC\N=C\c2ccccc2O

InChI

1S/C16H16N2O2/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20/h1-8,11-12,19-20H,9-10H2/b17-11+,18-12+

InChI key

VEUMANXWQDHAJV-JYFOCSDGSA-N

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一般描述

在丙酮溶液中,N,N′-(亚水杨基)乙二胺 (salen) 与氯化铁反应生成络合物 (Fe salen Cl)

应用

采用 N,N′-双(亚水杨基)乙二胺 (salen) 为配位剂,以流动注射火焰原子吸收光谱法 (FI-AAS) 在线预浓缩铜和铅

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

新产品

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分析证书(COA)

Lot/Batch Number

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F Janati Fard et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 74-82 (2012-07-04)
Co(III) salen complex with N,N'-dipyridoxyl (1,4-butanediamine) Schiff-base ligand as tetradentate ligand was synthesized and characterized by the elemental and spectroscopic analysis. The interaction of this complex with calf thymus DNA (ct DNA) has been investigated in vitro using UV absorption
Linus Chiang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(44), 14117-14127 (2012-09-22)
Square-planar nickel(II) complexes of salen ligands, N,N'-bis(3-tert-butyl-(5R)-salicylidene)-1,2-cyclohexanediamine), in which R=tert-butyl (1), OMe (2), and NMe(2) (3), were prepared and the electronic structure of the one-electron-oxidized species [1-3](+·) was investigated in solution. Cyclic voltammograms of [1-3] showed two quasi-reversible redox waves
Structure and Paramagnetism of Five-and Six-Co-ordinate N: N' Bis-salicylidene Ethylenediamine Iron (III) Chloride.
Gerloch M, et al.
Nature, 212, 809-810 (1966)
Erin E Podlesny et al.
Organic letters, 14(18), 4862-4865 (2012-09-04)
The selective oxidation of a series of functionalized 8,8'-hydroxylated binaphthols to binaphtho-para- and binaphtho-ortho-quinones has been realized using either a Co-salen catalyst or ortho-iodoxybenzoic acid. A unique spirocyclic bis-spironaphthalenone was also obtained in good yield via a phenyliodonium diacetate promoted
Lakshmi Kanta Das et al.
Dalton transactions (Cambridge, England : 2003), 41(36), 11009-11017 (2012-08-04)
Two new trinuclear hetero-metallic copper(II)-zinc(II) complexes [(CuL)(2)Zn(N(3))(2)] (1A and 1B) have been synthesized using [CuL] as a so-called "metalloligand" (where H(2)L = N,N'-bis(salicylidene)-1,3-propanediamine) and structurally characterized. Complexes 1A and 1B have the same molecular formula but crystallize in different crystal

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