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235202

Sigma-Aldrich

4-溴甲基-7-甲氧基香豆素

97%

别名:

BMC, Br-Mmc

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About This Item

经验公式（希尔记法）:
C11H9BrO3
CAS号:
35231-44-8
分子量:
269.09
Beilstein:
187211
EC 号:
252-448-3
MDL编号:
MFCD00006869
UNSPSC代码:
12352100
PubChem化学物质编号:
24854087
NACRES:
NA.22

质量水平

200

方案

97%

表单

solid

mp

213-215 °C (lit.)

溶解性

chloroform: soluble 20 mg/mL, clear, colorless to faintly yellow

荧光

λex 322 nm; λem 395 nm (after derivatization)

官能团

bromo
ester

SMILES字符串

COc1ccc2C(CBr)=CC(=O)Oc2c1

InChI

1S/C11H9BrO3/c1-14-8-2-3-9-7(6-12)4-11(13)15-10(9)5-8/h2-5H,6H2,1H3

InChI key

CTENSLORRMFPDH-UHFFFAOYSA-N

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相关类别

应用

用于各种天然存在的酸，包括胆汁和血栓烷 B2 的衍生化反应、TLC 和 HPLC 分离以及荧光分析。
脂肪酸的荧光标记。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000316436
0000316436
0000131291
0000115675
0000115676

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V Hagen et al.
Journal of photochemistry and photobiology. B, Biology, 53(1-3), 91-102 (2000-02-15)
New caged derivatives of hydrolysis-resistant 8-bromoadenosine cyclic 3',5'-monophosphate (8-Br-cAMP) and 8-bromoguanosine cyclic 3',5'-monophosphate (8-Br-cGMP) are described. The compounds are the axial and equatorial isomers of the (7-methoxycoumarin-4-yl)methyl (MCM) esters of cyclic nucleotides. Synthesis is accomplished by treatment of 4-bromomethyl-7-methoxycoumarin with
Brisa S Fernandes et al.
BMC medicine, 13, 289-289 (2015-12-02)
The neurotrophic hypothesis postulates that mood disorders such as bipolar disorder (BD) are associated with a lower expression of brain-derived neurotrophic factor (BDNF). However, its role in peripheral blood as a biomarker of disease activity and of stage for BD
D Allen Roberts et al.
BMC medicine, 13, 285-285 (2015-12-04)
Globally, countries are increasingly prioritizing the reduction of health inequalities and provision of universal health coverage. While national benchmarking has become more common, such work at subnational levels is rare. The timely and rigorous measurement of local levels and trends
Analytical Letters, 26, 429-429 (1993)
J H Wolf et al.
Journal of pharmaceutical and biomedical analysis, 10(2-3), 99-107 (1992-02-01)
A major part of modern analytical problem solving deals with the trace level determination of organic compounds and contaminants in biomedical, food and environmental samples. In the analysis of these samples chromatographic techniques play a predominant role. Unfortunately, however, even
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