蒸汽密度
>1 (vs air)
质量水平
检测方案
99%
形式
liquid
折射率
n20/D 1.511 (lit.)
bp
203-204 °C (lit.)
mp
9-10 °C (lit.)
密度
1.451 g/mL at 25 °C (lit.)
SMILES字符串
[O-][N+](=O)c1ccc(F)cc1F
InChI
1S/C6H3F2NO2/c7-4-1-2-6(9(10)11)5(8)3-4/h1-3H
InChI key
RJXOVESYJFXCGI-UHFFFAOYSA-N
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一般描述
已经使用带有模拟移动床（SMB）色谱模块的流动反应器研究了吗啉对 2,4-二氟硝基苯的亲核芳族取代。
应用
2,4-二氟硝基苯已用于合成以下物质：
- 通过磺化反应生成 2,4-二氟-5-硝基苯磺酸
- （±）-茶碱
- 树脂结合的 2-芳基氨基苯并咪唑
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
A direct synthesis of 2-arylpropenoic acid esters having nitro groups in the aromatic ring: a short synthesis of (?)-coerulescine and (?)-horsfiline.
Selvakumar N, et al.
Tetrahedron Letters, 43(50), 9175-9178 (2002)
Alexander G O'Brien et al.
Angewandte Chemie (International ed. in English), 51(28), 7028-7030 (2012-06-08)
Continuous synthesis meets continuous purification to produce pure products from crude reaction mixtures. In the nucleophilic aromatic substitution of 2,4-difluoronitrobenzene with morpholine the desired monosubstituted product can be continuously separated from the byproducts in a purity of over 99 %
U M Kremer
Biological chemistry Hoppe-Seyler, 371(9), 861-864 (1990-09-01)
2,4-Difluoro-5-nitrobenzenesulfonic acid has been synthesized by the sulfonation of 2,4-difluoronitrobenzene, and precipitated with KCl as the potassium sulfonate. The structure was confirmed by chemical and spectroscopic methods (IR, 1H-NMR, 13C-NMR, 19F-NMR, UV, MS and ultimate organic analysis). Lysozyme was cross-linked
A solid phase traceless synthesis of 2-arylaminobenzimidazoles.
Krchnak V, et al.
Tetrahedron Letters, 42(9), 1627-1630 (2001)
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