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Merck
CN

232017

Sigma-Aldrich

四氯-1,4-苯醌

99%

别名:

2,3,5,6-四氯-1,4-苯醌, 四氯对醌, 四氯苯醌

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About This Item

线性分子式:
C6Cl4(=O)2
CAS号:
分子量:
245.88
Beilstein:
393006
EC 号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

99%

形式

solid

mp

289 °C (dec.) (lit.)

SMILES字符串

ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O

InChI

1S/C6Cl4O2/c7-1-2(8)6(12)4(10)3(9)5(1)11

InChI key

UGNWTBMOAKPKBL-UHFFFAOYSA-N

基因信息

一般描述

Tetrachloro-1,4-benzoquinone (TCBQ) is a quinone compound with four chloride groups. The catalytic activity of quinone groups (benzoquinone) can be controlled by the chloride groups with large electronegativity.

应用

可与二苯乙烯衍生物、α,β-不饱和羰基化合物发生光诱导的环加成反应。荧光猝灭剂。
用于通过氧化环化反应合成二苯并呋喃。
TCBQ can form a nanocomposite with multi-walled carbon nanotubes (MWCNTs) on a graphite electrode for nicotinamide adenine dinucleotide (NADH) oxidation. It can also provide pseudocapacitance and can be used as an electrode material for the development of supercapacitors. It may be used as an organic cathode and act as a redox mediator for the fabrication of lithium ion batteries.

警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

农药列管产品

分析证书(COA)

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在文件库中查找您最近购买产品的文档。

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Journal of the Chemical Society. Perkin Transactions 1, 571-571 (1994)
Synthesis of a polyacrylonitrile/tetrachloro-1, 4-benzoquinone gel polymer electrolyte for high-performance Li-air batteries.
Bok K, et al.
Journal of Membrane Science (2018)
Tetsuya Takeya et al.
Organic letters, 9(15), 2807-2810 (2007-06-22)
A novel oxidative cyclization of quinone-arenols 5 leading to products 6 with a dibenzofuran-1,4-dione structure, which forms the core of several natural products, has been developed and applied to the synthesis of violet-quinone (4).
An Insoluble Benzoquinone-Based Organic Cathode for Use in Rechargeable Lithium-Ion Batteries.
Luo Z, et al.
Angewandte Chemie (International ed. in English), 56(41), 12561-12565 (2017)
J. Prakt. Chem./Chem.-Ztg., 335, 515-515 (1993)

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