227722
六氟磷酸银
98%, solid
别名:
Silver(I) hexafluorophosphate
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关于此项目
线性分子式:
AgPF6
化学文摘社编号:
分子量:
252.83
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
247-428-6
MDL number:
产品名称
六氟磷酸银, 98%
InChI key
SCQBROMTFBBDHF-UHFFFAOYSA-N
InChI
1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1
SMILES string
[Ag+].F[P-](F)(F)(F)(F)F
assay
98%
form
solid
reaction suitability
core: silver
reagent type: catalyst
mp
102 °C (dec.) (lit.)
Quality Level
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General description
六氟磷酸银可作为催化剂用于硫酰亚胺化（sulfimidation）、醛氢化转化为醇以及炔烃和羧酸的氢酰氧基化（hydroacyloxylation）。
Application
（六氟锑酸银）用于制备3,3′-二氰基二苯基乙炔银配位网络，以研究配体对网络结构的作用，以便研制新型材料。（六氟锑酸银）可制备银配合物的超分子网络。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Silver-Catalyzed Enantioselective Sulfimidation Mediated by Hydrogen Bonding Interactions
Annapureddy R, et al.
Angewandte Chemie (International Edition in English), 133, 7999-8005 (2021)
Journal of Organometallic Chemistry, 692, 4093-4093 (2007)
Silver-Catalyzed Hydrogenation of Aldehydes in Water
Jia Z, et al.
Angewandte Chemie (International Edition in English), 52, 11871-11874 (2013)
Gold (I)-catalyzed addition of carboxylic acids to alkynes
Chary B, et al.
The Journal of Organic Chemistry, 75, 7928-7931 (2010)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar
商品
Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.
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