所有图片(2)
About This Item
线性分子式:
AgPF6
CAS号:
分子量:
252.83
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
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![四 [3,5-双（三氟甲基）苯基] 硼酸钠](/deepweb/assets/sigmaaldrich/product/structures/251/439/7a621e74-bfd1-4a43-833c-09adfcc1e0b3/640/7a621e74-bfd1-4a43-833c-09adfcc1e0b3.png)
质量水平
方案
98%
表单
solid
反应适用性
core: silver
reagent type: catalyst
mp
102 °C (dec.) (lit.)
SMILES字符串
[Ag+].F[P-](F)(F)(F)(F)F
InChI
1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1
InChI key
SCQBROMTFBBDHF-UHFFFAOYSA-N
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一般描述
六氟磷酸银可作为催化剂用于硫酰亚胺化（sulfimidation）、醛氢化转化为醇以及炔烃和羧酸的氢酰氧基化（hydroacyloxylation）。
应用
（六氟锑酸银）用于制备3,3′-二氰基二苯基乙炔银配位网络，以研究配体对网络结构的作用，以便研制新型材料。（六氟锑酸银）可制备银配合物的超分子网络。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Journal of Organometallic Chemistry, 692, 4093-4093 (2007)
Silver-Catalyzed Hydrogenation of Aldehydes in Water
Jia Z, et al.
Angewandte Chemie (International Edition in English), 52, 11871-11874 (2013)
Gold (I)-catalyzed addition of carboxylic acids to alkynes
Chary B, et al.
The Journal of Organic Chemistry, 75, 7928-7931 (2010)
Silver-Catalyzed Enantioselective Sulfimidation Mediated by Hydrogen Bonding Interactions
Annapureddy R, et al.
Angewandte Chemie (International Edition in English), 133, 7999-8005 (2021)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar
商品
Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.
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