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质量水平
反应适用性
reaction type: Grignard Reaction
浓度
2.0 M in diethyl ether
密度
0.828 g/mL at 25 °C
SMILES字符串
CC(C)(C)[Mg]Cl
InChI
1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
InChI key
ZDRJSYVHDMFHSC-UHFFFAOYSA-M
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应用
tert-Butylmagnesium chloride solution can be used as a Grignard reagent:
- In the Fe-catalyzed cross-coupling reaction with chloroenynols.
- To synthesize alkyne-terminated polyhexylthiophenes.
警示用语:
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
靶器官
Central nervous system
补充剂危害
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
-40.0 °F - closed cup
闪点(°C)
-40 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Self-assembly of carbohydrate-block-poly (3-hexylthiophene) diblock copolymers into sub-10 nm scale lamellar structures
Macromolecules, 50, 3365-3376 (2017)
The Journal of organic chemistry, 72(10), 3868-3874 (2007-04-17)
Palladium-catalyzed hydrostannation of substituted Z- and E-enynols is discussed and compared. The regioselectivity of the H-Sn bond addition was found to be controlled by the geometry of the double bond (Z- or syn-directing effect) rather than the nature of its
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