224448
苯基氯化镁 溶液
2.0 M in THF
别名:
Chlorophenylmagnesium
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关于此项目
线性分子式:
C6H5MgCl
化学文摘社编号:
分子量:
136.86
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587900
InChI
1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
SMILES string
Cl[Mg]c1ccccc1
InChI key
GQONLASZRVFGHI-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
2.0 M in THF
density
~1.02 g/mL at 20 °C, 1.042 g/mL at 25 °C
Quality Level
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Application
苯基氯化镁 (PhMgCl) 溶液是一种常用的格氏试剂，用于合成 (-) - 苯羟基丙氨酸和 stephacidin B。它用于多种交叉偶联反应。 它也可以与氯化铝 (AlCl3) 一起在可充电镁电池中用作电解质溶液。
Packaging
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Other Notes
25°C 以下储存可能会形成结晶镁盐。将容器移动至温暖位置，偶尔轻轻涡旋应使固体重新溶解
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Enantioselective synthesis of stephacidin B.
Herzon S, et al.
Journal of the American Chemical Society, 127(15), 5342-5344 (2005)
Functional group tolerant Kumada- Corriu- Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles: Catalysis by a nickel pincer complex permits the coupling of functionalized Grignard reagents.
Vechorkin O, et al.
Journal of the American Chemical Society, 131(28), 9756-9766 (2009)
Electrolyte solutions with a wide electrochemical window for rechargeable magnesium batteries.
Mizrahi O, et al.
Journal of the Electrochemical Society, 155(2), A103-A109 (2008)
Asymmetric synthesis of pyrrolidinoindolines. Application for the practical total synthesis of (−)-phenserine
Huang A, et al.
Journal of the American Chemical Society, 126(43), 14043-14053 (2004)
Nickel-Catalyzed Cross-Coupling of Aryl Chlorides with Aryl Grignard Reagents.
B ohm VPW, et al.
Angewandte Chemie (International Edition in English), 39(9), 1602-1604 (2000)
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