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Merck
CN

208248

乙酰丙酮铝

98%

别名:

2,4-乙酰丙酮铝, Al(acac)3

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关于此项目

线性分子式:
Al(C5H7O2)3
化学文摘社编号:
13963-57-0
分子量:
324.31
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
24852500
EC Number:
237-741-6
Beilstein/REAXYS Number:
4157942
MDL number:
MFCD00000013

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产品名称

乙酰丙酮铝, 98%

InChI key

KILURZWTCGSYRE-LNTINUHCSA-K

InChI

1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

SMILES string

CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

assay

98%

form

solid

reaction suitability

core: aluminum

bp

315 °C (lit.)

mp

190-193 °C (lit.)

Quality Level

200

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相关类别

Application

乙酰丙酮铝可用于：
  • 升华法制备透明超疏水的薄水铝石和二氧化硅薄膜，
  • 化学气相沉积氧化铝薄膜，
  • 作为催化剂。

General description

乙酰丙酮铝不溶于水，但可溶于有机溶剂。在高温下与碱、酸、水反应。它可以通过 AlCl3 与乙酰丙酮反应制备。

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

244.4 °F

flash_point_c

118 °C

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ3897
MKCZ3899
MKCZ3898
MKCZ3203
MKCW9572

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Aluminum oxide thin films prepared by chemical vapor deposition from aluminum acetylacetonate
Maruyama T, et al.
Applied Physics Letters, 60(3), 322-323 (1992)
Preparation of transparent superhydrophobic boehmite and silica films by sublimation of aluminum acetylacetonate.
Nakajima A, et al.
Advanced Mat., 11(16), 1365-1368 (1999)
M Favarato et al.
Brain research, 569(2), 330-335 (1992-01-13)
To determine the influence of the metal coordination sphere on the permeability of the blood-brain barrier (BBB), rats were injected intraperitoneally with aluminum lactate (Al(lact)3), aluminum acetylacetonate (Al(acac)3), aluminum maltolate (Al(malt)3) at pH 7.5, or with physiological saline. Two h
B Corain et al.
Biomedical and environmental sciences : BES, 1(3), 283-287 (1988-10-01)
Aluminum acetylacetonate was administered to New Zealand white rabbits as liposome preparations and was found to distribute approximately 1:1 between water and phosphatidylcholine dipalmitoyl vesicles. Biochemical monitoring proved that after 2 weeks of daily injection of 40 micrograms of Al(III)
Yannick Millot et al.
Solid state nuclear magnetic resonance, 21(1-2), 21-43 (2002-04-13)
The increasing development and application of the multiple-quantum MAS NMR for half-integer quadrupole spins has led to various RF pulse sequences for improving the excitation of multiple-quantum coherences and their conversion to single-quantum coherences. As a result, several conventions for
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